@article{UBHD-68795472, author={Ebner, Fabian and Sigmund, Lukas M. and Greb, Lutz}, title={Metal-ligand cooperativity of the calix(4)pyrrolato aluminate}, subtitle={triggerable C-C bond formation and rate control in catalysis}, year={2020}, pages={17266-17272}, language={eng}, issn={1521-3757}, volume={132}, number={39}, note={Im Titel steht die 4 in eckiger Klammer ; First published: 23 June 2020 ; Gesehen am 02.11.2021}, journal={Angewandte Chemie}, doi={10.1002/ange.202007717}, url={https://doi.org/10.1002/ange.202007717}, library={UB}, } @article{UBHD-68795470, author={Ebner, Fabian and Sigmund, Lukas M. and Greb, Lutz}, title={Metal-ligand cooperativity of the calix(4)pyrrolato aluminate}, subtitle={triggerable C-C bond formation and rate control in catalysis}, year={2020}, pages={17118-17124}, language={eng}, issn={1521-3773}, volume={59}, number={39}, note={Im Titel steht die 4 in eckiger Klammer ; Gesehen am 02.11.2021}, journal={Angewandte Chemie}, doi={10.1002/anie.202007717}, url={https://doi.org/10.1002/anie.202007717}, library={UB}, } @article{UBHD-69328706, author={Erdmann, Philipp and Sigmund, Lukas M. and Schmitt, Manuel and H{\"a}hnel, Theresa and Dittmer, Linus Bjarne and Greb, Lutz}, title={A benchmark study of DFT-computed p-block element Lewis pair formation enthalpies against experimental calorimetric data}, year={2024}, pages={1-7}, language={eng}, issn={1439-7641}, volume={25}, note={Gesehen am 07.04.2025}, journal={ChemPhysChem}, doi={10.1002/cphc.202400761}, } @article{UBHD-69252582, author={Erdmann, Philipp and Schmitt, Manuel and Sigmund, Lukas M. and Kr{\"a}mer, Felix and Breher, Frank and Greb, Lutz}, title={How to deal with charge in the ranking of lewis acidity}, subtitle={critical evaluation of an extensive set of cationic lewis acids}, year={2024}, pages={1-8}, language={eng}, issn={1521-3773}, volume={63}, note={Artikelversion online: April 8, 2024 ; Gesehen am 11.09.2024}, journal={Angewandte Chemie}, doi={10.1002/anie.202403356}, } @article{UBHD-68638757, author={Greb, Lutz and Ebner, Fabian and Ginzburg, Yael and Sigmund, Lukas M.}, title={Element-ligand cooperativity with p-block Elements}, year={2020}, pages={3030-3047}, language={eng}, issn={1099-0682}, number={32}, note={Gesehen am 18.09.2020}, journal={European journal of inorganic chemistry}, doi={10.1002/ejic.202000449}, url={https://doi.org/10.1002/ejic.202000449}, library={UB}, } @article{UBHD-69210745, author={Kistner, Lucas and Sigmund, Lukas M. and Grieser, Fabian Frank and Krauss, Julian and Leingang, Simone and Kaifer, Elisabeth and Greb, Lutz and Himmel, Hans-J{\"o}rg}, title={Metal-free B-B dehydrocoupling reaction of a simple borane adduct}, subtitle={convenient access to a nucleophilic diborane(4)}, year={2024}, pages={1-9}, language={eng}, issn={1521-3773}, volume={63}, note={Gesehen am 03.05.2024}, journal={Angewandte Chemie}, doi={10.1002/anie.202317462}, } @article{UBHD-69273583, author={Kohl, Senta J. and Sigmund, Lukas M. and Schmitt, Manuel and Greb, Lutz}, title={Nitrogen monoxide and calix[4]pyrrolato aluminate}, subtitle={structural constraint enabled NO dimerization}, year={2024}, pages={10803-10809}, language={eng}, issn={2041-6539}, volume={15}, number={28}, note={Zuerst ver{\"o}ffentlicht: 17. Juni 2024 ; Gesehen am 14.11.2024}, journal={Chemical science}, doi={10.1039/D4SC02378A}, } @article{UBHD-68970521, author={Ruppert, Heiko and Sigmund, Lukas M. and Greb, Lutz}, title={Calix(4)pyrroles as ligands}, subtitle={recent progress with a focus on the emerging p-block element chemistry}, year={2021}, pages={11751-11763}, language={eng}, issn={1364-548X}, volume={57}, number={89}, note={Im Titel steht 4 in eckiger Klammer ; Gesehen am 05.10.2022}, journal={Chemical communications}, doi={10.1039/D1CC05120B}, } @article{UBHD-68970150, author={Sch{\"o}n, Florian and Sigmund, Lukas M. and Schneider, Friederike and Hartmann, Deborah and Wiebe, Matthew A. and Manners, Ian and Greb, Lutz}, title={Calix(4)pyrrolato aluminate catalyzes the dehydrocoupling of phenylphosphine borane to high molar weight polymers}, year={2022}, pages={1-5}, language={eng}, issn={1521-3773}, volume={61}, note={Im Titel steht 4 in eckiger Klammer ; Version of record online: March 29, 2022 ; Gesehen am 04.10.2022}, journal={Angewandte Chemie}, doi={10.1002/anie.202202176}, } @article{UBHD-68803998, author={Sigmund, Lukas M. and Ebner, Fabian and J{\"o}st, Christoph and Spengler, Jonas and G{\"o}nnheimer, Nils and Hartmann, Deborah and Greb, Lutz}, title={An air-stable, neutral phenothiazinyl radical with substantial radical stabilization energy}, year={2020}, pages={3152-3156}, language={eng}, issn={1521-3765}, volume={26}, number={14}, note={First published: 16 January 2020 ; Gesehen am 22.11.2021}, journal={Chemistry - a European journal}, doi={10.1002/chem.201905238}, url={https://doi.org/10.1002/chem.201905238}, library={UB}, } @article{UBHD-68990705, author={Sigmund, Lukas M. and Ehlert, Christopher and Enders, Markus and Graf, J{\"u}rgen and Gryn’ova, Ganna and Greb, Lutz}, title={Dioxygen activation and pyrrole α-cleavage with calix(4)pyrrolato aluminates}, subtitle={enzyme model by structural constraint}, year={2021}, pages={15632-15640}, language={eng}, issn={1521-3773}, volume={60}, number={28}, note={First published: 06 May 2021 ; Gesehen am 29.11.2022}, journal={Angewandte Chemie}, doi={10.1002/anie.202104916}, url={https://doi.org/10.1002/anie.202104916}, library={UB}, } @article{UBHD-69064580, author={Sigmund, Lukas M. and Ehlert, Christopher and Enders, Markus and Graf, J{\"u}rgen and Gryn’ova, Ganna and Greb, Lutz}, title={Disauerstoffaktivierung und Pyrrol-α-Spaltung mit Calix[4]pyrrolatoaluminaten}, subtitle={Enzymmodell durch strukturellen Zwang}, year={2021}, pages={15761-15769}, language={ger}, issn={1521-3757}, volume={133}, number={28}, note={Gesehen am 12.04.2023}, journal={Angewandte Chemie}, doi={10.1002/ange.202104916}, url={https://doi.org/10.1002/ange.202104916}, library={UB}, } @article{UBHD-68970155, author={Sigmund, Lukas M. and Maier, Rouven and Greb, Lutz}, title={The inversion of tetrahedral p-block element compounds}, subtitle={general trends and the relation to the second-order Jahn-Teller effect}, year={2022}, pages={510-521}, language={eng}, issn={2041-6539}, volume={13}, number={2}, note={Gesehen am 04.10.2022}, journal={Chemical science}, doi={10.1039/D1SC05395G}, } @article{UBHD-69222861, author={Sigmund, Lukas M. and S. V., Shree Sowndarya and Albers, Andreas and Erdmann, Philipp and Paton, Robert S. and Greb, Lutz}, title={Predicting lewis acidity}, subtitle={machine learning the fluoride Ion affinity of p-block-atom-based molecules}, year={2024}, pages={1-10}, language={eng}, issn={1521-3773}, volume={63}, note={Gesehen am 12.06.2024}, journal={Angewandte Chemie}, doi={10.1002/anie.202401084}, } @article{UBHD-68654867, author={Sigmund, Lukas M. and Greb, Lutz}, title={Reversible OH-bond activation and amphoterism by metal-ligand cooperativity of calix[4]pyrrolato aluminate}, year={2020}, pages={9611-9616}, language={eng}, issn={2041-6539}, volume={11}, number={35}, note={Gesehen am 28.10.2020}, journal={Chemical science}, doi={10.1039/D0SC03602A}, } @article{UBHD-68938887, author={Sigmund, Lukas M. and Ehlert, Christopher and Gryn’ova, Ganna and Greb, Lutz}, title={Stereoinversion of tetrahedral p-block element hydrides}, year={2022}, pages={1-11}, language={eng}, issn={1089-7690}, volume={156}, note={Gesehen am 07.07.2022}, journal={The journal of chemical physics}, doi={10.1063/5.0090267}, } @book{UBHD-69211454, author={Sigmund, Lukas M.}, title={Structural constraint and flexibility in the chemistry of Lewis-acidic p-block atom-based molecules}, address={Heidelberg}, year={2024}, pages={1 Online-Ressource (260, XXXI Seiten)}, language={eng}, school={Dissertation, Heidelberg University, 2024}, doi={10.11588/heidok.00034642}, keywords={Anorganische Chemie / Computational chemistry / Maschinelles Lernen}, url={http://nbn-resolving.de/urn:nbn:de:bsz:16-heidok-346426}, library={UB}, } @book{UBHD-69223170, author={Sigmund, Lukas M.}, organization={Universit{\"a}t Heidelberg}, title={Structural constraint and flexibility in the chemistry of Lewis-acidic p-block atom-based molecules}, address={Heidelberg}, year={2024}, pages={260, XXXI Seiten}, language={eng}, school={Dissertation, Heidelberg University, 2024}, keywords={Anorganische Chemie / Computational chemistry / Maschinelles Lernen}, library={UB [Signatur: 2024 T 11]}, }