Synthesis of different classes of six-membered gold(I) NHC complexes by the isonitrile route

• Verfasst von: Wurm, Thomas [VerfasserIn]
• Verfasst von: Mulks, Florian [VerfasserIn]
• Verfasst von: Böhling, Constantin R. N. [VerfasserIn]
• Verfasst von: Riedel, Dominic [VerfasserIn]
• Verfasst von: Zargaran, Poorya [VerfasserIn]
• Verfasst von: Rudolph, Matthias [VerfasserIn]
• Verfasst von: Rominger, Frank [VerfasserIn]
• Verfasst von: Hashmi, A. Stephen K. [VerfasserIn]
• Titel: Synthesis of different classes of six-membered gold(I) NHC complexes by the isonitrile route
• Verf.angabe: Thomas Wurm, Florian Mulks, Constantin R.N. Böhling, Dominic Riedel, Poorya Zargaran, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
• Umfang: 9 S.
• Fussnoten: Gesehen am 29.09.2016
• Titel Quelle: Enthalten in: Organometallics
• Jahr Quelle: 2016
• Band/Heft Quelle: 35(2016), 8, S. 1070-1078
• ISSN Quelle: 1520-6041
• DOI: doi:10.1021/acs.organomet.6b00023
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1563968479

Abstract

Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.