Status: Bibliographieeintrag
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| Verfasst von: | Stockinger, Skrollan Carina [VerfasserIn]  |
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| | Spallek, Markus Jürgen [VerfasserIn] |
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| | Trapp, Oliver [VerfasserIn] |
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| Titel: | Investigation of novel immobilized 3-(perfluoroalkanoyl)-(1R)-camphorate nickel complexes in enantioselective complexation gas chromatography |
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| Verf.angabe: | Skrollan Stockinger, Markus J. Spallek, Oliver Trapp |
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| E-Jahr: | 2012 |
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| Jahr: | 9 August 2012 |
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| Umfang: | 6 S. |
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| Fussnoten: | Gesehen am 28.08.2020 |
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| Titel Quelle: | Enthalten in: Journal of chromatography / A |
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| Ort Quelle: | New York, NY [u.a.] : Science Direct, 1958 |
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| Jahr Quelle: | 2012 |
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| Band/Heft Quelle: | 1269(2012), Seite 346-351 |
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| ISSN Quelle: | 1873-3778 |
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| Abstract: | Novel 3-(perfluoroalkanoyl)-(1R)-camphorate nickel complexes immobilized to poly(dimethylsiloxane) phases are presented. Immobilized 3-(perfluoroalkanoyl)-(1R)-camphorate nickel complexes with a trifluoromethyl (CF3; nickel(II)-bis[(1R,4S)-3-trifluoromethanoyl-10-propylenoxycamphor]-polysiloxane Ni(tfpc)2@PS) and a heptafluoropropyl-substituent (C3F7; nickel(II)-bis[(1R,4S)-3-heptafluorobutanoyl-10-propylenoxycamphor]-polysiloxane Ni(hfpc)2@PS) were synthesized, characterized and immobilized to polysiloxane. Ni(hfpc)2@PS was immobilized with a selector content of 38% and their enantioseparation ability was compared to selector concentrations of 4% and 20%. The influence of the perfluorinated moiety as well as the effect of the selector concentration on enantioseparations were investigated. Based on different functionalized organic compounds the quality of enantioseparation was analyzed and compared. |
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| DOI: | doi:10.1016/j.chroma.2012.08.012 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: http://dx.doi.org/10.1016/j.chroma.2012.08.012 |
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| | Volltext: http://www.sciencedirect.com/science/article/pii/S0021967312011983 |
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| | DOI: https://doi.org/10.1016/j.chroma.2012.08.012 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | Chiral separation |
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| | Chiral stationary phase |
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| | Chirasil-Metal |
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| | Enantioselective gas chromatography |
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| | Perfluorinated moiety |
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| | Selector concentration |
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| K10plus-PPN: | 1572225203 |
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| Verknüpfungen: | → Zeitschrift |
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Investigation of novel immobilized 3-(perfluoroalkanoyl)-(1R)-camphorate nickel complexes in enantioselective complexation gas chromatography / Stockinger, Skrollan Carina [VerfasserIn]; 9 August 2012 (Online-Ressource)
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