The first catalytic synthesis of an acrylate from CO2 and an alkene

• Verfasst von: Lejkowski, Michael L. [VerfasserIn]
• Verfasst von: Lindner, Ronald [VerfasserIn]
• Verfasst von: Kageyama, Takeharu [VerfasserIn]
• Verfasst von: Bódizs, Gabriella É. [VerfasserIn]
• Verfasst von: Pleßow, Philipp [VerfasserIn]
• Verfasst von: Rominger, Frank [VerfasserIn]
• Verfasst von: Hofmann, Peter [VerfasserIn]
• Verfasst von: Limbach, Michael [VerfasserIn]
• Titel: The first catalytic synthesis of an acrylate from CO2 and an alkene
• Titelzusatz: a rational approach
• Verf.angabe: Michael L. Lejkowski, Ronald Lindner, Takeharu Kageyama, Gabriella É Bódizs, Philipp N. Plessow, Imke B. Müller, Ansgar Schäfer, Frank Rominger, Peter Hofmann, Cornelia Futter, Stephan A. Schunk, and Michael Limbach
• Umfang: 9 S.
• Fussnoten: Gesehen am 07.08.2018 ; Dedicated to Professor Dieter Seebach on the occasion of his 75th birthday
• Titel Quelle: Enthalten in: Chemistry - a European journal
• Jahr Quelle: 2012
• Band/Heft Quelle: 18(2012), 44, S. 14017-14025
• ISSN Quelle: 1521-3765
• DOI: doi:10.1002/chem.201201757
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1578341833

Abstract

For more than three decades the catalytic synthesis of acrylates from the cheap and abundantly available C1 building block carbon dioxide and alkenes has been an unsolved problem in catalysis research, both in academia and industry. Herein, we describe a homogeneous catalyst based on nickel that permits the catalytic synthesis of the industrially highly relevant acrylate sodium acrylate from CO2, ethylene, and a base, as demonstrated, at this stage, by a turnover number of greater than 10 with respect to the metal.