Cobalt alkyl complexes of a new family of chiral 1,3-Bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation

• Verfasst von: Sauer, Désirée C. [VerfasserIn]
• Verfasst von: Wadepohl, Hubert [VerfasserIn]
• Verfasst von: Gade, Lutz H. [VerfasserIn]
• Titel: Cobalt alkyl complexes of a new family of chiral 1,3-Bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation
• Verf.angabe: Désirée C. Sauer, Hubert Wadepohl, and Lutz H. Gade
• E-Jahr: 2012
• Jahr: November 12, 2012
• Umfang: 11 S.
• Teil: volume:51
• Teil: year:2012
• Teil: number:23
• Teil: pages:12948-12958
• Teil: extent:11
• Fussnoten: Gesehen am 13.09.2018
• Titel Quelle: Enthalten in: Inorganic chemistry
• Ort Quelle: Washington, DC : American Chemical Society, 1962
• Jahr Quelle: 2012
• Band/Heft Quelle: 51(2012), 23, Seite 12948-12958
• ISSN Quelle: 1520-510X
• DOI: doi:10.1021/ic3020749
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 158094664X

Abstract

Synopsis: A new family of chiral 1,3-bis(2-pyridylimino)isoindolate ligands with various substitution patterns was prepared using achiral starting materials. Their cobalt alkyl complexes were synthesized and characterized. The application of this enantiomerically pure compounds in the asymmetric hydrosilylation of ketones was tested giving the corresponding alcohols in high yields and enantioselectivity.