Large-scale compositional and electronic Inhomogeneities in CH3NH3PbI3 perovskites and their effect on device performance

• Verfasst von: Sun, Qing [VerfasserIn]
• Verfasst von: Faßl, Paul [VerfasserIn]
• Verfasst von: Vaynzof, Yana [VerfasserIn]
• Titel: Large-scale compositional and electronic Inhomogeneities in CH3NH3PbI3 perovskites and their effect on device performance
• Verf.angabe: Qing Sun, Paul Fassl, and Yana Vaynzof
• E-Jahr: 2018
• Jahr: May 21, 2018
• Umfang: 7 S.
• Fussnoten: Im Titel ist „3“ jeweils tiefgestellt ; Gesehen am 25.04.2019
• Titel Quelle: Enthalten in: ACS applied energy materials
• Ort Quelle: Washington, DC : ACS Publications, 2018
• Jahr Quelle: 2018
• Band/Heft Quelle: 1(2018), 6, Seite 2410-2416
• ISSN Quelle: 2574-0962
• DOI: doi:10.1021/acsaem.8b00509
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1663605882

Abstract

Photovoltaic devices based on lead halide perovskite materials are under extensive investigation due to their remarkably high efficiencies. However, it has become evident that the photovoltaic performance of these devices shows wide distributions, even across individual perovskite samples, resulting in the practice of presenting performance histograms, rather than single values. We demonstrate that these variations in performance are related to the large-scale compositional and electronic inhomogeneities of perovskite films, which we characterize using X-ray and ultraviolet photoemission spectroscopy mapping. These inhomogeneities are observed for three different fabrication methods for the perovskite layers, and while they are unaltered by storage in nitrogen and dry air, long-term exposure to vacuum increases the homogeneity of the surface structure. We demonstrate that perovskite films with a nonuniform surface structure result in broadly varying photovoltaic performance despite seemingly similar bulk properties such as absorption and microstructure.