On the basic extraction properties of a phenyl trifluoromethyl sulfone-based GANEX system containing CyMe4-BTBP and TBP

• Verfasst von: Halleröd, Jenny [VerfasserIn]
• Verfasst von: Wagner, Christoph [VerfasserIn]
• Verfasst von: Panak, Petra [VerfasserIn]
• Titel: On the basic extraction properties of a phenyl trifluoromethyl sulfone-based GANEX system containing CyMe4-BTBP and TBP
• Verf.angabe: Jenny Halleröd, Christian Ekberg, Thea Authen, Laura Bertolo, Mu Lin, Bohumír Grüner, Jaroslav Švehla, Christoph Wagner, Andreas Geist, Petra Panak, and Emma Aneheim
• E-Jahr: 2018
• Jahr: 18 Jul 2018
• Umfang: 13 S.
• Fussnoten: Im Titel die 4 ist tiefgestellt ; Gesehen am 21.08.2019
• Titel Quelle: Enthalten in: Solvent extraction and ion exchange
• Ort Quelle: Philadelphia, PA : Taylor & Francis, 1983
• Jahr Quelle: 2018
• Band/Heft Quelle: 36(2018), 4, Seite 360-372
• ISSN Quelle: 1532-2262
• DOI: doi:10.1080/07366299.2018.1497043
• Datenträger: Online-Ressource
• Sprache: eng
• Sach-SW: CyMe4-BTBP
• Sach-SW: FS-13
• Sach-SW: GANEX
• Sach-SW: metal extraction
• Sach-SW: Solvent extraction
• Sach-SW: TBP
• K10plus-PPN: 1671734483

Abstract

A Grouped ActiNide EXtraction (GANEX) process for the extraction of actinides from used nuclear fuel for transmutation purposes has been investigated. The studied solvent consists of phenyl trifluoromethyl sulfone (FS-13), CyMe4-BTBP, and TBP, a combination that has previously shown promising results. The time to reach extraction equilibrium for the system has been found to be less than 20 min. A 2:1 complex has been found between CyMe4-BTBP and americium(III) or curium(III), whereas plutonium(IV) and CyMe4-BTBP create a 1:1 complex. The extraction of fission product is low in the system.