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| Online-Ressource |
Verfasst von: | Herrmann, Maximilian [VerfasserIn] |
| Cao, Le [VerfasserIn] |
| Sihler, Holger [VerfasserIn] |
| Platt, Ulrich [VerfasserIn] |
| Gutheil, Eva [VerfasserIn] |
Titel: | On the contribution of chemical oscillations to ozone depletion events in the polar spring |
Verf.angabe: | Maximilian Herrmann, Le Cao, Holger Sihler, Ulrich Platt, and Eva Gutheil |
E-Jahr: | 2019 |
Jahr: | 13 August 2019 |
Umfang: | 30 S. |
Fussnoten: | Gesehen am 07.10.2019 |
Titel Quelle: | Enthalten in: Atmospheric chemistry and physics |
Ort Quelle: | Katlenburg-Lindau : EGU, 2001 |
Jahr Quelle: | 2019 |
Band/Heft Quelle: | 19(2019), 15, Seite 10161-10190 |
ISSN Quelle: | 1680-7324 |
Abstract: | Abstract. This paper presents a numerical study of the oscillations (or recurrences) of tropospheric ozone depletion events (ODEs) using the further-developed one-dimensional KInetic aNALysis of reaction mechanics with Transport (KINAL-T) chemistry transport model. Reactive bromine is the major contributor to the occurrence of ODEs. After the termination of an ODE, the reactive bromine in the air is deposited onto aerosols or on the snow surface, and the ozone may regenerate via NOx-catalyzed photochemistry or by turbulent transport from the free troposphere into the boundary layer. The replenished ozone then is available for the next cycle of autocatalytic bromine release (bromine explosion) leading to another ODE. The oscillation periods are found to be as short as 5 d for the purely chemically NOx-driven oscillation and 30 d for a diffusion-driven oscillation. An important requirement for oscillation of ODEs to occur is found to be a sufficiently strong inversion layer. In a parameter study, the dependence of the oscillation period on the nitrogen oxides' concentration, the inversion layer strength, the ambient temperature, the aerosol density, and the solar radiation is investigated. Parameters controlling the oscillation of ODEs are discussed. |
URL: | kostenfrei: Volltext: https://doi.org/10.5194/acp-19-10161-2019 |
| Verlag: https://www.atmos-chem-phys.net/19/10161/2019/ |
Datenträger: | Online-Ressource |
Sprache: | eng |
K10plus-PPN: | 1678203912 |
Verknüpfungen: | → Zeitschrift |
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Lokale URL UB: | Zum Volltext |
On the contribution of chemical oscillations to ozone depletion events in the polar spring / Herrmann, Maximilian [VerfasserIn]; 13 August 2019 (Online-Ressource)
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