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| Verfasst von: | Benneckendorf, Frank S. [VerfasserIn]  |
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| | Hillebrandt, Sabina [VerfasserIn] |
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| | Rohnacher, Valentina [VerfasserIn] |
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| | Jänsch, Daniel [VerfasserIn] |
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| | Freudenberg, Jan [VerfasserIn] |
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| | Beck, Sebastian [VerfasserIn] |
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| | Pucci, Annemarie [VerfasserIn] |
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| | Bunz, Uwe H. F. [VerfasserIn] |
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| Titel: | Structure-property relationship of phenylene-based self-assembled monolayers for record low work function of indium tin oxide |
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| Verf.angabe: | Frank S. Benneckendorf, Sabina Hillebrandt, Florian Ullrich, Valentina Rohnacher, Sebastian Hietzschold, Daniel Jänsch, Jan Freudenberg, Sebastian Beck, Eric Mankel, Wolfram Jaegermann, Annemarie Pucci, Uwe H.F. Bunz, and Klaus Müllen |
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| E-Jahr: | 2018 |
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| Jahr: | 20 June 2018 |
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| Umfang: | 7 S. |
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| Fussnoten: | Gesehen am 11.03.2020 |
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| Titel Quelle: | Enthalten in: The journal of physical chemistry letters |
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| Ort Quelle: | Washington, DC : ACS, 2010 |
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| Jahr Quelle: | 2018 |
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| Band/Heft Quelle: | 9(2018), 13, Seite 3731-3737 |
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| ISSN Quelle: | 1948-7185 |
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| Abstract: | Studying the structure-property relations of tailored dipolar phenyl and biphenylphosphonic acids, we report self-assembled monolayers with a significant decrease in the work function (WF) of indium-tin oxide (ITO) electrodes. Whereas the strengths of the dipoles are varied through the different molecular lengths and the introduction of electron-withdrawing fluorine atoms, the surface energy is kept constant through the electron-donating N,N-dimethylamine head groups. The self-assembled monolayer formation and its modification of the electrodes are investigated via infrared reflection absorption spectroscopy, contact angle measurements, and photoelectron spectroscopy. The WF decrease in ITO correlates with increasing molecular dipoles. The lowest ever recorded WF of 3.7 eV is achieved with the fluorinated biphenylphosphonic acid. |
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| DOI: | doi:10.1021/acs.jpclett.8b01242 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext: https://doi.org/10.1021/acs.jpclett.8b01242 |
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| | DOI: https://doi.org/10.1021/acs.jpclett.8b01242 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| K10plus-PPN: | 1692260901 |
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| Verknüpfungen: | → Zeitschrift |
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Structure-property relationship of phenylene-based self-assembled monolayers for record low work function of indium tin oxide / Benneckendorf, Frank S. [VerfasserIn]; 20 June 2018 (Online-Ressource)
