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| Verfasst von: | Schießl, Jasmin [VerfasserIn]  |
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| | Schulmeister, Jürgen [VerfasserIn] |
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| | Doppiu, Angelino [VerfasserIn] |
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| | Wörner, Eileen [VerfasserIn] |
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| | Rudolph, Matthias [VerfasserIn] |
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| | Karch, Ralf [VerfasserIn] |
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| | Hashmi, A. Stephen K. [VerfasserIn] |
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| Titel: | An industrial perspective on counter anions in gold catalysis |
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| Titelzusatz: | underestimated with respect to “Ligand effects” |
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| Verf.angabe: | Jasmin Schießl, Jürgen Schulmeister, Angelino Doppiu, Eileen Wörner, Matthias Rudolph, Ralf Karch, A. Stephen K. Hashmi |
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| E-Jahr: | 2018 |
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| Jahr: | 25 March 2018 |
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| Umfang: | 10 S. |
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| Fussnoten: | Gesehen am 21.04.2020 |
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| Titel Quelle: | Enthalten in: Advanced synthesis & catalysis |
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| Ort Quelle: | Weinheim : Wiley-VCH, 2001 |
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| Jahr Quelle: | 2018 |
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| Band/Heft Quelle: | 360(2018), 13, Seite 2493-2502 |
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| ISSN Quelle: | 1615-4169 |
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| Abstract: | The conversion of a variety of well-known test reactions, representing the key reactivity patterns of gold catalysis, were analyzed by GC and 1H NMR. The study is focused on establishing of a strategical approach for the consideration of ligand influence and counter anion influence during the catalyst optimization including an industrial perspective. The study shows a dominance of the counter anion, a dominance which up to now has been neglected in most of the routine screenings. In addition, a drastic substrate-dependency became obvious, even a marginal variation of the substrate already could strongly effect the catalytic activity and change the optimal counter anion or ligand. Based on the collected data a strategic concept for an efficient screening for a specific substrate is introduced, this concept can serve as an important guideline for catalyst optimization in homogeneous gold catalysis. |
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| DOI: | doi:10.1002/adsc.201800233 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext: https://doi.org/10.1002/adsc.201800233 |
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| | Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201800233 |
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| | DOI: https://doi.org/10.1002/adsc.201800233 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | Alkynes |
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| | allenes |
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| | catalyst optimization |
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| | counter anion |
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| | gold |
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| | ligand |
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| K10plus-PPN: | 1695549422 |
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| Verknüpfungen: | → Zeitschrift |
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¬An¬ industrial perspective on counter anions in gold catalysis / Schießl, Jasmin [VerfasserIn]; 25 March 2018 (Online-Ressource)
