| |  Online-Ressource |
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| Verfasst von: | Comba, Peter [VerfasserIn]  |
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| | Fukuzumi, Shunichi [VerfasserIn] |
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| | Koke, Carsten [VerfasserIn] |
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| | Martin, Bodo [VerfasserIn] |
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| | Rensland, Anna-Maria [VerfasserIn] |
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| | Straub, Johannes [VerfasserIn] |
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| Titel: | A bispidine iron(IV)-oxo complex in the entatic state |
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| Verf.angabe: | Peter Comba, Shunichi Fukuzumi, Carsten Koke, Bodo Martin, Anna-Maria Löhr, Johannes Straub |
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| E-Jahr: | 2016 |
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| Jahr: | 28 July 2016 |
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| Umfang: | 5 S. |
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| Fussnoten: | Gesehen am 04.05.2020 |
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| Titel Quelle: | Enthalten in: Angewandte Chemie / International edition |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1962 |
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| Jahr Quelle: | 2016 |
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| Band/Heft Quelle: | 55(2016), 37, Seite 11129-11133 |
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| ISSN Quelle: | 1521-3773 |
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| Abstract: | For a series of FeIV=O complexes with tetra- and pentadentate bispidine ligands, the correlation of their redox potentials with reactivity, involving a variety of substrates for alkane hydroxylation (HAT), alkene epoxidation, and phosphine and thioether oxidation (OAT) are reported. The redox potentials span approximately 350 mV and the reaction rates over 8 orders of magnitude. From the experimental data and in comparison with published studies it emerges that electron transfer and the driving force are of major importance, and this is also supported by the DFT-based computational analysis. The striking difference of reactivity of two isomeric systems with pentadentate bispidines is found to be due to a destabilization of the S=1 ground state of one of the ferryl isomers, and this is supported by the experimentally determined redox potentials and published stability constants with a series of first-row transition metal ions with these two isomeric ligands. |
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| DOI: | doi:10.1002/anie.201605099 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/anie.201605099 |
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| | Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201605099 |
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| | DOI: https://doi.org/10.1002/anie.201605099 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | coordination chemistry |
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| | density functional calculations |
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| | homogeneous catalysis |
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| | iron bispidine complexes |
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| | redox potentials |
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| K10plus-PPN: | 1697041892 |
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| Verknüpfungen: | → Zeitschrift |
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¬A¬ bispidine iron(IV)-oxo complex in the entatic state / Comba, Peter [VerfasserIn]; 28 July 2016 (Online-Ressource)
