Status: Bibliographieeintrag
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| Verfasst von: | Ottmann, Alexander [VerfasserIn]  |
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| | Zakharova, G. S. [VerfasserIn] |
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| | Ehrstein, Benjamin [VerfasserIn] |
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| | Klingeler, Rüdiger [VerfasserIn] |
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| Titel: | Electrochemical performance of single crystal belt-like NH4V3O8 as cathode material for lithium-ion batteries |
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| Verf.angabe: | A. Ottmann, G.S. Zakharova, B. Ehrstein, R. Klingeler |
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| E-Jahr: | 2015 |
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| Jahr: | 15 June 2015 |
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| Umfang: | 6 S. |
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| Fussnoten: | Gesehen am 25.06.2020 |
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| Titel Quelle: | Enthalten in: Electrochimica acta |
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| Ort Quelle: | New York, NY [u.a.] : Elsevier, 1959 |
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| Jahr Quelle: | 2015 |
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| Band/Heft Quelle: | 174(2015), Seite 682-687 |
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| ISSN Quelle: | 1873-3859 |
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| Abstract: | NH4V3O8 with belt-like morphology has been synthesized via a hydrothermal process, using acetic acid as acidulant. The resulting phase-pure NH4V3O8 microcrystals have smooth surfaces and are typically 25-45μm long, 2-15μm wide, and 0.6-1.2μm thick. Electrochemical studies by means of cyclic voltammetry and galvanostatic cycling show that the pristine material is a suitable host for reversible Li+ de-/intercalation. Analysis of the peak currents from cyclic voltammetry by means of the Randles-Sevcik equation suggests that the Li+ de-/intercalation is diffusion-controlled with D∼5·10−15cm2s−1. The maximum discharge capacity, at 20mAg−1, amounts to 299mAhg−1. At 90mAg−1, it is still 201mAhg−1 with a capacity retention of 90% in the 100th cycle, indicating the belt-like NH4V3O8 being a promising candidate for application as cathode material in secondary lithium-ion batteries. |
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| DOI: | doi:10.1016/j.electacta.2015.06.027 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1016/j.electacta.2015.06.027 |
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| | Volltext: http://www.sciencedirect.com/science/article/pii/S0013468615013985 |
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| | DOI: https://doi.org/10.1016/j.electacta.2015.06.027 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | Ammonium trivanadate |
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| | Belt-like microcrystal |
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| | Cathode material |
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| | Hydrothermal synthesis |
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| | Lithium-ion battery |
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| K10plus-PPN: | 1702123383 |
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| Verknüpfungen: | → Zeitschrift |
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Electrochemical performance of single crystal belt-like NH4V3O8 as cathode material for lithium-ion batteries / Ottmann, Alexander [VerfasserIn]; 15 June 2015 (Online-Ressource)
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