Status: Bibliographieeintrag
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| Verfasst von: | Wang, Kunpeng [VerfasserIn]  |
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| | Ottmann, Alexander [VerfasserIn] |
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| | Zhang, Jianxiu [VerfasserIn] |
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| | Meyer, Hans-Peter [VerfasserIn] |
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| | Klingeler, Rüdiger [VerfasserIn] |
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| Titel: | Synthesis, growth mechanism, and morphology control of LiFe1/3Mn1/3Co1/3PO4 via a microwave-assisted hydrothermal method |
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| Verf.angabe: | Kunpeng Wang, Alexander Ottmann, Jianxiu Zhang, Hans-Peter Meyer, Rüdiger Klingeler |
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| E-Jahr: | 2015 |
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| Jahr: | 23 March 2015 |
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| Umfang: | 10 S. |
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| Teil: | volume:30 |
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| | year:2015 |
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| | number:7 |
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| | pages:914-923 |
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| | extent:10 |
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| Fussnoten: | Gesehen am 29.06.2020 ; Im Titel sind "1/3" und "4" in LiFe1/3Mn1/3Co1/3PO4 tiefgestellt |
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| Titel Quelle: | Enthalten in: Journal of materials research |
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| Ort Quelle: | Berlin : Springer, 1986 |
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| Jahr Quelle: | 2015 |
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| Band/Heft Quelle: | 30(2015), 7, Seite 914-923 |
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| ISSN Quelle: | 2044-5326 |
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| Abstract: | LiFe1/3Mn1/3Co1/3PO4 (LFMC) has been synthesized by a microwave-assisted hydrothermal technique. During the crystal growth, two evolutionary routes coexist and compete with each other after the nuclei have been stably formed. One of them is the continuous growth of single particles and the other one is agglomeration. The size and morphology of the products are determined by the interplay of the two competing routes. The growth morphology is quantitatively analyzed from first principle calculations. A phase diagram is constructed, which guides to control the morphology by adjusting CM and pH. Static magnetic properties imply long range antiferromagnetic order below TN = 39 K and a paramagnetic Curie-Weiss-like behavior with θ = 75 K and peff = 5.51 μB at high temperatures. Cyclic voltammetry shows two distinct peaks corresponding to the Fe2+/Fe3+ and Co2+/Co3+ redox couples, respectively, whereas the Mn2+/Mn3+ redox couple is not observed due to its sluggish kinetics induced by the Jahn-Teller effect of Mn3+. |
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| DOI: | doi:10.1557/jmr.2015.63 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1557/jmr.2015.63 |
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| | Volltext: https://www.cambridge.org/core/journals/journal-of-materials-research/article/synthesis-growth-mechanism-and-morphology- ... |
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| | DOI: https://doi.org/10.1557/jmr.2015.63 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | LiFe1/3Mn1/3Co1/3PO4 |
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| | lithium-ion batteries |
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| | microwave-assisted hydrothermal synthesis |
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| K10plus-PPN: | 1702843777 |
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| Verknüpfungen: | → Zeitschrift |
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Synthesis, growth mechanism, and morphology control of LiFe1/3Mn1/3Co1/3PO4 via a microwave-assisted hydrothermal method / Wang, Kunpeng [VerfasserIn]; 23 March 2015 (Online-Ressource)
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