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Status: Bibliographieeintrag

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Verfasst von:Eberle, Benjamin [VerfasserIn]   i
 Hübner, Olaf [VerfasserIn]   i
 Ziesak, Alexandra Sabrina [VerfasserIn]   i
 Kaifer, Elisabeth [VerfasserIn]   i
 Himmel, Hans-Jörg [VerfasserIn]   i
Titel:What makes a strong organic electron donor (or acceptor)?
Verf.angabe:Benjamin Eberle, Olaf Hübner, Alexandra Ziesak, Elisabeth Kaifer, and Hans-Jörg Himmel
E-Jahr:2015
Jahr:April 27, 2015
Umfang:13 S.
Fussnoten:Gesehen am 06.07.2020
Titel Quelle:Enthalten in: Chemistry - a European journal
Ort Quelle:Weinheim : Wiley-VCH, 1995
Jahr Quelle:2015
Band/Heft Quelle:21(2015), 23, Seite 8578-8590
ISSN Quelle:1521-3765
Abstract:Organic electron donors are of importance for a number of applications. However, the factors that are essential for a directed design of compounds with desired reduction power are not clear. Here, we analyze these factors in detail. The intrinsic reduction power, which neglects the environment, has to be separated from extrinsic (e.g., solvent) effects. This power could be quantified by the gas-phase ionization energy. The experimentally obtained redox potentials in solution and the calculated ionization energies in a solvent (modeled with the conductor-like screening model (COSMO)) include both intrinsic and extrinsic factors. An increase in the conjugated π-system of organic electron donors leads to an increase in the intrinsic reduction power, but also decreases the solvent stabilization. Hence, intrinsic and extrinsic effects compete against each other; generally the extrinsic effects dominate. We suggest a simple relationship between the redox potential in solution and the gas-phase ionization energy and the volume of an organic electron donor. We finally arrive at formulas that allow for an estimate of the (gas-phase) ionization energy of an electron donor or the (gas-phase) electron affinity of an electron acceptor from the measured redox potentials in solution. The formulas could be used for neutral organic molecules with no or only small static dipole moment and relatively uniform charge distribution after oxidation/reduction.
DOI:doi:10.1002/chem.201406597
URL:Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.

Volltext ; Verlag: https://doi.org/10.1002/chem.201406597
 Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201406597
 DOI: https://doi.org/10.1002/chem.201406597
Datenträger:Online-Ressource
Sprache:eng
Sach-SW:electron transfer
 ionization potentials
 redox chemistry
 reduction
 solvent effects
K10plus-PPN:1703728351
Verknüpfungen:→ Zeitschrift

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