Status: Bibliographieeintrag
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| Verfasst von: | Gmeiner, Julia Renate [VerfasserIn]  |
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| | Seibicke, Max [VerfasserIn] |
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| | Lang, Carolin [VerfasserIn] |
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| | Gaertner, Ute [VerfasserIn] |
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| | Trapp, Oliver [VerfasserIn] |
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| Titel: | An immobilised Grubbs 2nd generation catalyst for application in flow-through devices |
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| Verf.angabe: | Julia Gmeiner, Max Seibicke, Carolin Lang, Ute Gärtner, and Oliver Trapp |
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| E-Jahr: | 2014 |
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| Jahr: | May 28, 2014 |
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| Umfang: | 7 S. |
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| Fussnoten: | Gesehen am 10.08.2020 |
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| Titel Quelle: | Enthalten in: Advanced synthesis & catalysis |
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| Ort Quelle: | Weinheim : Wiley-VCH, 2001 |
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| Jahr Quelle: | 2014 |
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| Band/Heft Quelle: | 356(2014), 9, Seite 2081-2087 |
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| ISSN Quelle: | 1615-4169 |
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| Abstract: | An improved immobilised Grubbs 2nd generation catalyst and its application in flow-through devices, shown for on-column reaction gas chromatography (ocRGC), has been studied. The coupling of a reaction capillary and a separation column in GC/MS allows direct reaction monitoring and analysis of conversion as well as reaction kinetics. The presented permanently bonded N-heterocyclic carbene ligand shows a great stability and activity in ring closing metathesis reactions. A salt-free approach was used to generate the carbene ligand, which can be directly monitored by mass spectrometry. The very flexible design of the immobilised ligand system in reaction channels and capillaries of flow through systems allows the preparation of various catalysts using a broad variety of metal precursors. This strategy of immobilised catalytically active complexes offers a wide range of on-column reactions combinable with fast reaction screening by high throughput experimentation. |
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| DOI: | doi:10.1002/adsc.201301182 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/adsc.201301182 |
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| | Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201301182 |
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| | DOI: https://doi.org/10.1002/adsc.201301182 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | carbene ligands |
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| | heterogeneous catalysis |
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| | high throughput screening |
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| | homogeneous catalysis |
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| | metathesis |
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| K10plus-PPN: | 1726701026 |
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| Verknüpfungen: | → Zeitschrift |
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¬An¬ immobilised Grubbs 2nd generation catalyst for application in flow-through devices / Gmeiner, Julia Renate [VerfasserIn]; May 28, 2014 (Online-Ressource)
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