Status: Bibliographieeintrag
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| Verfasst von: | Manzano, Rubén [VerfasserIn]  |
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| | Wurm, Thomas [VerfasserIn] |
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| | Rominger, Frank [VerfasserIn] |
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| | Hashmi, A. Stephen K. [VerfasserIn] |
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| Titel: | Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes |
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| Verf.angabe: | Rubén Manzano, Thomas Wurm, Frank Rominger, and A. Stephen K. Hashmi |
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| E-Jahr: | 2014 |
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| Jahr: | April 25, 2014 |
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| Umfang: | 5 S. |
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| Fussnoten: | Gesehen am 13.08.2020 |
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| Titel Quelle: | Enthalten in: Chemistry - a European journal |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1995 |
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| Jahr Quelle: | 2014 |
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| Band/Heft Quelle: | 20(2014), 23, Seite 6844-6848 |
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| ISSN Quelle: | 1521-3765 |
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| Abstract: | Abstract A number of saturated abnormal N-heterocyclic carbene (NHC) complexes of gold, in combination with KBArF4 as activator, were successfully applied in the chemoselective addition of hydrazine to alkynes. The reaction proceeds even at room temperature, which was not possible to date with gold catalysts. The reaction can be applied to a number of substituted arylalkynes. With alkylalkynes the yields are low. The saturated abnormal NHC ligands are resistant to isomerization to the saturated normal NHC coordination mode under basic reaction conditions. Under acidic conditions, a simple protonation at the nitrogen atom not neighboring the carbene center was observed and unambiguously characterized by an X-ray crystal-structure analysis. Computational studies confirm that such an isomerization would be highly exothermic, the observed kinetic stability probably results from the need to shift two protons in such a process. |
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| DOI: | doi:10.1002/chem.201402560 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/chem.201402560 |
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| | Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201402560 |
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| | DOI: https://doi.org/10.1002/chem.201402560 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Bibliogr. Hinweis: | Erscheint auch als : Druck-Ausgabe: Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes. - 2014 |
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| Sach-SW: | alkynes |
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| | carbene ligands |
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| | density functional calculations |
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| | gold |
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| | hydrazones |
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| K10plus-PPN: | 1726969967 |
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| Verknüpfungen: | → Zeitschrift |
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Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes / Manzano, Rubén [VerfasserIn]; April 25, 2014 (Online-Ressource)
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