Poly(aryleneethynylene)s (PAE) as paradigmatic sensor cores

• Verfasst von: Bunz, Uwe H. F. [VerfasserIn]
• Verfasst von: Seehafer, Kai [VerfasserIn]
• Verfasst von: Bender, Markus [VerfasserIn]
• Verfasst von: Porz, Michael [VerfasserIn]
• Titel: Poly(aryleneethynylene)s (PAE) as paradigmatic sensor cores
• Verf.angabe: Uwe H.F. Bunz, Kai Seehafer, Markus Bender and Michael Porz
• E-Jahr: 2015
• Jahr: 7 July 2015
• Umfang: 15 S.
• Fussnoten: Gesehen am 21.10.2020
• Titel Quelle: Enthalten in: Royal Society of ChemistryChemical Society reviews
• Ort Quelle: London : Soc., 1980
• Jahr Quelle: 2015
• Band/Heft Quelle: 44(2015), 13, Seite 4322-4336
• ISSN Quelle: 1460-4744
• DOI: doi:10.1039/C4CS00267A
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1736144464

Abstract

We describe poly(aryleneethynylene)s (PAE) as powerful sensor cores. We discuss concepts (super quenching, molecular wire effect, multivalency) that were developed using PAEs and also the relationship that connects side chain structure (polar, polyelectrolyte, etc., number of ionic groups per repeat, position) and optical properties such as quantum yields. In the second part of the review we discuss applications of PAEs in their interaction with sensor targets; metal cations, fluoride and other anions, explosives, proteins and whole cells being the target for PAEs, while cationic PAEs have been used for the transfection of eukaryotic cells with RNA.