Status: Bibliographieeintrag
Standort: ---
Exemplare:
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| Online-Ressource |
Verfasst von: | Koschabek, René [VerfasserIn]  |
| Gleiter, Rolf [VerfasserIn]  |
| Rominger, Frank [VerfasserIn]  |
Titel: | Synthesis and properties of cryptands with a thioether bridge and π-donors |
Titelzusatz: | silver(I) and copper(I)-complexes |
Verf.angabe: | René Koschabek, Rolf Gleiter, and Frank Rominger |
Jahr: | 2006 |
Jahr des Originals: | 2005 |
Umfang: | 12 S. |
Fussnoten: | Published online: December 13, 2005 ; Gesehen am 23.10.2020 |
Titel Quelle: | Enthalten in: European journal of inorganic chemistry |
Ort Quelle: | Weinheim : Wiley-VCH, 1998 |
Jahr Quelle: | 2006 |
Band/Heft Quelle: | (2006), 3, Seite 609-620 |
ISSN Quelle: | 1099-0682 |
Abstract: | The syntheses of seven bridgehead diazabicycloalkanes are reported. The bridges are represented by either a thioether chain and two 3-hexyne units (4 and 6-8), one selenoether chain and two 3-hexyne units (5), or one dithioether chain and two 4,4′-diethylbiphenyl units (9, 10). X-ray investigations reveal for 4-10 the in/in conformation at the bridgehead nitrogen atoms. Reactions with CuI triflate yield the endohedral CuI complexes of 4-6. Endohedral complexes of 6, 7, and 10 were isolated with silver triflate. X-ray investigations and spectroscopic studies on the metal complexes reveal interactions between the metal ion and the nitrogen-, chalcogen-, and π-units. In addition to the bicyclic systems 4-10 we synthesized the tripodal systems 28-33 in a one-pot reaction. In the cases of 28 and 33 we were able to isolate the corresponding AgI complexes. X-ray studies show an interaction between the metal ion and the nitrogen atom and one double bond of each of the three adjacent phenyl rings. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) |
DOI: | doi:10.1002/ejic.200500685 |
URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/ejic.200500685 |
| Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200500685 |
| DOI: https://doi.org/10.1002/ejic.200500685 |
Datenträger: | Online-Ressource |
Sprache: | eng |
Sach-SW: | Alkynes |
| Cage compounds |
| Copper |
| Silver |
K10plus-PPN: | 1736493949 |
Verknüpfungen: | → Zeitschrift |
Synthesis and properties of cryptands with a thioether bridge and π-donors / Koschabek, René [VerfasserIn]; 2006 (Online-Ressource)
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