| |  Online-Ressource |
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| Verfasst von: | Tindall, Daniel James [VerfasserIn]  |
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| | Mader, Steffen [VerfasserIn] |
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| | Kindler, Alois [VerfasserIn] |
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| | Rominger, Frank [VerfasserIn] |
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| | Hashmi, A. Stephen K. [VerfasserIn] |
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| | Schaub, Thomas [VerfasserIn] |
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| Titel: | Selective and scalable synthesis of sugar alcohols by homogeneous asymmetric hydrogenation of unprotected ketoses |
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| Verf.angabe: | Daniel J. Tindall, Steffen Mader, Alois Kindler, Frank Rominger, A. Stephen K. Hashmi, and Thomas Schaub |
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| Jahr: | 2021 |
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| Jahr des Originals: | 2020 |
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| Umfang: | 5 S. |
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| Teil: | volume:60 |
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| | year:2021 |
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| | number:2 |
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| | pages:721-725 |
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| | extent:5 |
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| Fussnoten: | First published: 14 September 2020 ; Gesehen am 14.04.2021 |
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| Titel Quelle: | Enthalten in: Angewandte Chemie / International edition |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1962 |
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| Jahr Quelle: | 2021 |
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| Band/Heft Quelle: | 60(2021), 2, Seite 721-725 |
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| ISSN Quelle: | 1521-3773 |
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| Abstract: | Sugar alcohols are of great importance for the food industry and are promising building blocks for bio-based polymers. Industrially, they are produced by heterogeneous hydrogenation of sugars with H2, usually with none to low stereoselectivities. Now, we present a homogeneous system based on commercially available components, which not only increases the overall yield, but also allows a wide range of unprotected ketoses to be diastereoselectively hydrogenated. Furthermore, the system is reliable on a multi-gram scale allowing sugar alcohols to be isolated in large quantities at high atom economy. |
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| DOI: | doi:10.1002/anie.202009790 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/anie.202009790 |
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| | Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202009790 |
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| | DOI: https://doi.org/10.1002/anie.202009790 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | asymmetric catalysis |
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| | hydrogenation |
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| | industrial chemistry |
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| | ruthenium |
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| | sugar alcohol |
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| K10plus-PPN: | 1737618494 |
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| Verknüpfungen: | → Zeitschrift |
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Selective and scalable synthesis of sugar alcohols by homogeneous asymmetric hydrogenation of unprotected ketoses / Tindall, Daniel James [VerfasserIn]; 2021 (Online-Ressource)
