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| Verfasst von: | Bru, Miriam [VerfasserIn]  |
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| | Dehn, Richard [VerfasserIn] |
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| | Teles, J. Henrique [VerfasserIn] |
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| | Deuerlein, Stephan [VerfasserIn] |
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| | Danz, Manuel [VerfasserIn] |
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| | Müller, Imke B. [VerfasserIn] |
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| | Limbach, Michael [VerfasserIn] |
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| Titel: | Ruthenium carbenes supported on mesoporous silicas as highly active and selective hybrid catalysts for olefin metathesis reactions under continuous flow |
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| Verf.angabe: | Miriam Bru, Richard Dehn, J. Henrique Teles, Stephan Deuerlein, Manuel Danz, Imke B. Müller, and Michael Limbach |
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| E-Jahr: | 2013 |
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| Jahr: | July 12, 2013 |
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| Umfang: | 11 S. |
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| Fussnoten: | Gesehen am 08.12.2020 |
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| Titel Quelle: | Enthalten in: Chemistry - a European journal |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1995 |
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| Jahr Quelle: | 2013 |
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| Band/Heft Quelle: | 19(2013), 35, Seite 11661-11671 |
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| ISSN Quelle: | 1521-3765 |
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| Abstract: | In the search for a highly active and selective heterogenized metathesis catalyst, we systematically varied the pore geometry and size of various silica-based mesoporous (i.e., MCM-41, MCM-48, and SBA-15) and microporous (ZSM-5 and MWW) versus macroporous materials (D11-10 and Aerosil 200), besides other process parameters (temperature, dilution, and mean residence time). The activity and, especially, selectivity of such “linker-free” supports for ruthenium metathesis catalysts were evaluated in the cyclodimerization of cis-cyclooctene to form 1,9-cyclohexadecadiene, a valuable intermediate in the flavor and fragrance industry. The optimized material showed not only exceptionally high selectivity to the valuable product, but also turned out to be a truly heterogeneous catalyst with superior activity relative to the unsupported homogeneous complex. |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201203893 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | cyclooligomerization |
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| | macrocycles |
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| | mesoporous materials |
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| | metathesis |
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| | ruthenium |
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| | supported catalysts |
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| K10plus-PPN: | 1742285317 |
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| Verknüpfungen: | → Zeitschrift |
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Ruthenium carbenes supported on mesoporous silicas as highly active and selective hybrid catalysts for olefin metathesis reactions under continuous flow / Bru, Miriam [VerfasserIn]; July 12, 2013 (Online-Ressource)
