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Verfasst von:Hendrich, Christoph [VerfasserIn]   i
 Hannibal, Valentin D. [VerfasserIn]   i
 Eberle, Lukas [VerfasserIn]   i
 Hertwig, Leif E. [VerfasserIn]   i
 Zschieschang, Ute [VerfasserIn]   i
 Rominger, Frank [VerfasserIn]   i
 Rudolph, Matthias [VerfasserIn]   i
 Klauk, Hagen [VerfasserIn]   i
 Hashmi, A. Stephen K. [VerfasserIn]   i
Titel:Gold-catalyzed synthesis of π-extended carbazole-based systems and their application as organic semiconductors
Verf.angabe:Christoph M. Hendrich, Valentin D. Hannibal, Lukas Eberle, Leif E. Hertwig, Ute Zschieschang, Frank Rominger, Matthias Rudolph, Hagen Klauk, and A. Stephen K. Hashmi
E-Jahr:2021
Jahr:01 February 2021
Umfang:7 S.
Fussnoten:Version of record online: Februar 1, 2021 ; Gesehen am 07.05.2021
Titel Quelle:Enthalten in: Advanced synthesis & catalysis
Ort Quelle:Weinheim : Wiley-VCH, 2001
Jahr Quelle:2021
Band/Heft Quelle:363(2021), 5, Seite 1401-1407
ISSN Quelle:1615-4169
Abstract:Herein we describe a gold-catalyzed bidirectional synthesis of N-heteropolycyclic compounds bearing carbazole moieties - namely π-extended benzodicarbazoles and π-extended indolocarbazoles. Overall, four previously unknown core structures were synthesized. This approach is convergent, modular and the gold-catalyzed key step comprises of a cascade reaction starting from stable di-azido compounds. The obtained molecules were fully characterized and their optical and electronic properties as well as their performance in organic thin-film transistors generated by vacuum deposition were studied. Charge-carrier mobilities of up to 0.3 cm2/Vs were measured.
DOI:doi:10.1002/adsc.202001461
URL:kostenfrei: Volltext: https://doi.org/10.1002/adsc.202001461
 kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.202001461
 DOI: https://doi.org/10.1002/adsc.202001461
Datenträger:Online-Ressource
Sprache:eng
Sach-SW:azides
 cascade cyclization
 Homogeneous gold catalysis
 organic semiconductors
 thin-film transistors
K10plus-PPN:1757480382
Verknüpfungen:→ Zeitschrift
 
 
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