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| Verfasst von: | Eppel, Daniel [VerfasserIn]  |
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| | Penert, Philipp [VerfasserIn] |
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| | Stemmer, Johanna [VerfasserIn] |
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| | Bauer, Christina [VerfasserIn] |
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| | Rudolph, Matthias [VerfasserIn] |
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| | Brückner, Margit [VerfasserIn] |
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| | Rominger, Frank [VerfasserIn] |
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| | Hashmi, A. Stephen K. [VerfasserIn] |
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| Titel: | Environmentally friendly, photochemical access to [N^C^N] AuIII pincer complexes by oxidative addition |
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| Verf.angabe: | Daniel Eppel, Philipp Penert, Johanna Stemmer, Christina Bauer, Matthias Rudolph, Margit Brückner, Frank Rominger, and A. Stephen K. Hashmi |
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| E-Jahr: | 2021 |
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| Jahr: | June 16, 2021 |
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| Umfang: | 5 S. |
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| Fussnoten: | Im Titel sind die Zeichen III hochgestellt ; First published: 30 April 2021 ; Gesehen am 08.06.2021 |
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| Titel Quelle: | Enthalten in: Chemistry - a European journal |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1995 |
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| Jahr Quelle: | 2021 |
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| Band/Heft Quelle: | 27(2021), 34, Seite 8673-8677 |
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| ISSN Quelle: | 1521-3765 |
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| Abstract: | Starting from commercially available DMSAuCl and diazonium salts, cationic [ ]AuIII complexes were synthesized in a selective, photosensitizer-free, photochemical reaction by irradiation with blue LED light. This new protocol represents the first easy synthesis of these types of pincer complexes in moderate to excellent yield starting from a readily available gold(I) precursor with nitrogen as the only by-product. Owing to the disadvantages of known protocols, especially the toxicity in the case of a transmetalation with mercury or the necessity for a mostly twofold excess of a gold precursor, this method offers an attractive alternative towards this kind of gold(III) complexes. In addition, the first arylated [ ]Au(III) pincer complex was synthesized by using this technology. |
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| DOI: | doi:10.1002/chem.202100035 |
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| URL: | kostenfrei: Volltext: https://doi.org/10.1002/chem.202100035 |
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| | kostenfrei: Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202100035 |
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| | DOI: https://doi.org/10.1002/chem.202100035 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | diazonium salts |
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| | gold complexes |
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| | oxidative addition |
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| | photosensitizer free compounds |
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| K10plus-PPN: | 1760021423 |
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| Verknüpfungen: | → Zeitschrift |
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| Lokale URL UB: |  Zum Volltext |
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Environmentally friendly, photochemical access to [N^C^N] AuIII pincer complexes by oxidative addition / Eppel, Daniel [VerfasserIn]; June 16, 2021 (Online-Ressource)
