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Verfasst von:Eppel, Daniel [VerfasserIn]   i
 Eryiğit, Alpay [VerfasserIn]   i
 Rudolph, Matthias [VerfasserIn]   i
 Brückner, Margit [VerfasserIn]   i
 Rominger, Frank [VerfasserIn]   i
 Asiri, Abdullah Mohamed [VerfasserIn]   i
 Hashmi, A. Stephen K. [VerfasserIn]   i
Titel:Mechanochemical gold(III)-carbon bond formation
Verf.angabe:Daniel Eppel, Alpay Eryiğit, Matthias Rudolph, Margit Brückner, Frank Rominger, Abdullah M. Asiri, and A. Stephen K. Hashmi
E-Jahr:2021
Jahr:07 April 2021
Umfang:5 S.
Fussnoten:Version of record online: May 6, 2021 ; Gesehen am 08.06.2021
Titel Quelle:Enthalten in: Angewandte Chemie. International edition
Ort Quelle:Weinheim : Wiley-VCH, 1998
Jahr Quelle:2021
Band/Heft Quelle:60(2021), 24, Seite 13636-13640
ISSN Quelle:1521-3773
Abstract:Starting from a [(MeOC^N^C)AuCl] complex as precursor, a direct substitution by C,H-activation from sp-, sp2- or sp3-C,H-bonds under basic conditions in a planetary ball mill was achieved. Because of the extraordinary photophysical properties of the target compounds, this protocol provides an easy access to a highly valued complex class. In contrast to existing protocols, no pre-functionalization of the starting materials is necessary and the use of expensive transition metal catalysts can be avoided, which makes this application appealing also for industrial purposes. In addition the methodology was not restricted to pincer complexes, which was demonstrated by the substitution of chelate type [(tpy)AuCl2] complexes.
DOI:doi:10.1002/anie.202017065
URL:kostenfrei: Volltext: https://doi.org/10.1002/anie.202017065
 kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202017065
 DOI: https://doi.org/10.1002/anie.202017065
Datenträger:Online-Ressource
Sprache:eng
Sach-SW:(C^N^C)Au complexes
 ball mill
 C
 H-activation
 mechanochemistry
K10plus-PPN:1760042439
Verknüpfungen:→ Zeitschrift
 
 
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