| Online-Ressource |
Verfasst von: | Wagner, Hannah [VerfasserIn]  |
| Ansmann, Nils [VerfasserIn]  |
| Gentner, Timon [VerfasserIn]  |
| Wadepohl, Hubert [VerfasserIn]  |
| Ballmann, Joachim [VerfasserIn]  |
Titel: | The multifaceted palladium chemistry of 2,2′-diphosphinotolanes |
Verf.angabe: | Hannah K. Wagner, Nils Ansmann, Timon Gentner, Hubert Wadepohl, and Joachim Ballmann |
E-Jahr: | 2021 |
Jahr: | March 11, 2021 |
Umfang: | 9 S. |
Fussnoten: | Gesehen am 11.06.2021 |
Titel Quelle: | Enthalten in: Organometallics |
Ort Quelle: | Washington, DC : ACS Publ., 1982 |
Jahr Quelle: | 2021 |
Band/Heft Quelle: | 40(2021), 6, Seite 804-812 |
ISSN Quelle: | 1520-6041 |
Abstract: | The 2,2′-bis(diisopropylphosphino)tolane 1 was reacted with various palladium precursors to afford a surprisingly diverse array of palladium(II) and palladium(I) complexes. The conventional cationic [PCCP]PdCl+ pincer-type complex 2 was readily obtained by starting from 1 and an in situ generated PdCl+ fragment. Upon chloropalladation of 2 via reaction with a chloride source, a novel vinyl-palladium pincer complex (3) featuring a new C-Cl bond was produced quantitatively. The newly formed C-Cl bond in 3 may be cleaved by addition of AgBF4, which led to the regeneration of 2. Treatment of 1 with (MeCN)2PdCl2 afforded 3 in a single step, while the analogous reaction between 1 and [(η3-allyl)PdCl]2 did not result in chloride or allyl addition. Instead, the alkyne was attacked by one of the phosphines to afford the cationic CArY-MIC palladium complex 4 (CArY-MIC = cyclic (aryl)(ylidic) mesoionic carbene). Upon reaction of 1 with dibenzylidene acetone palladium(0) precursors, two alkynes were coupled to afford the novel palladol 5. When Pd(CNR)2 (R = tBu, Cy) was employed instead of the latter palladium(0) precursors, yet another product was isolated: namely, a dinuclear Pd(I)-Pd(I) complex. In this complex, both palladium atoms are located within the pocket of the ligand and stabilized by isonitrile coligands (CNR with R = tBu for 6a and R = Cy for 6b). The latter isonitriles may be exchanged reversibly for carbon monoxide, as shown by in situ NMR spectroscopy. The finding that five significantly different palladium complexes (2-6) have been isolated by starting from a single phosphino alkyne is discussed in the context of phosphino-palladium-catalyzed alkyne transformations. |
DOI: | doi:10.1021/acs.organomet.1c00052 |
URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext: https://doi.org/10.1021/acs.organomet.1c00052 |
| DOI: https://doi.org/10.1021/acs.organomet.1c00052 |
Datenträger: | Online-Ressource |
Sprache: | eng |
K10plus-PPN: | 1760311073 |
Verknüpfungen: | → Zeitschrift |
¬The¬ multifaceted palladium chemistry of 2,2′-diphosphinotolanes / Wagner, Hannah [VerfasserIn]; March 11, 2021 (Online-Ressource)