Interpenetrated frameworks with anisotropic pore structures from a tetrahedral pyridine ligand

• Verfasst von: Geyer, Florian Ludwig [VerfasserIn]
• Verfasst von: Rominger, Frank [VerfasserIn]
• Verfasst von: Vogtland, Maximilian [VerfasserIn]
• Verfasst von: Bunz, Uwe H. F. [VerfasserIn]
• Titel: Interpenetrated frameworks with anisotropic pore structures from a tetrahedral pyridine ligand
• Verf.angabe: Florian L. Geyer, Frank Rominger, Maximilian Vogtland, and Uwe H.F. Bunz
• E-Jahr: 2015
• Jahr: 19 June 2015
• Umfang: 6 S.
• Teil: volume:15
• Teil: year:2015
• Teil: number:7
• Teil: pages:3539-3544
• Teil: extent:6
• Fussnoten: Gesehen am 10.08.2021
• Titel Quelle: Enthalten in: Crystal growth & design
• Ort Quelle: Washington, DC : ACS Publ., 2001
• Jahr Quelle: 2015
• Band/Heft Quelle: 15(2015), 7, Seite 3539-3544
• ISSN Quelle: 1528-7505
• DOI: doi:10.1021/acs.cgd.5b00719
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1766011888

Abstract

Herein we investigate metal-organic frameworks (MOFs) employing the tetrahedral building block tetrakis(4-(pyridin-4-ylethynyl)phenyl)silane (1) as a structure-generating feature. Combining 1 with a series of different metal ions gives wildly different MOF topologies, porosities, and properties. The frameworks discussed deviate from the common construction principles of MOFs as both the ligand and the metal center impose their coordination geometry on the overall network. The resulting networks show attractive and unusual void distributions, yet with properly controlled transition metal ion geometries, these MOFs show a rational structural grammar with respect to their structures.