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Verfasst von:Haaf, Sebastian [VerfasserIn]   i
 Kaifer, Elisabeth [VerfasserIn]   i
 Wadepohl, Hubert [VerfasserIn]   i
 Himmel, Hans-Jörg [VerfasserIn]   i
Titel:Use of crown ether functions as secondary Coordination Spheres for the Manipulation of Ligand-Metal Intramolecular Electron Transfer in Copper-Guanidine Complexes
Verf.angabe:Sebastian Haaf, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel
Jahr:2021
Umfang:12 S.
Fussnoten:First published: 24 August 2020 ; Gesehen am 05.11.2021
Titel Quelle:Enthalten in: Chemistry - a European journal
Ort Quelle:Weinheim : Wiley-VCH, 1995
Jahr Quelle:2021
Band/Heft Quelle:27(2021), 3, Seite 959-970
ISSN Quelle:1521-3765
Abstract:Intramolecular electron transfer (IET) between a redox-active organic ligand and a metal in a complex is of fundamental interest and used in a variety of applications. In this work it is demonstrated that secondary coordination sphere motifs can be applied to trigger a radical change in the electronic structure of copper complexes with a redox-active guanidine ligand through ligand-metal IET. Hence, crown ether functions attached to the ligand allow the manipulation of the degree of IET between the guanidine ligand and the copper atom through metal encapsulation.
DOI:doi:10.1002/chem.202003469
URL:kostenfrei: Volltext: https://doi.org/10.1002/chem.202003469
 kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202003469
 DOI: https://doi.org/10.1002/chem.202003469
Datenträger:Online-Ressource
Sprache:eng
Sach-SW:copper
 guanidine
 intramolecular electron transfer
 redox-active ligands
 secondary coordination sphere
K10plus-PPN:1776279891
Verknüpfungen:→ Zeitschrift
 
 
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