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| Online-Ressource |
Verfasst von: | Haaf, Sebastian [VerfasserIn]  |
| Kaifer, Elisabeth [VerfasserIn]  |
| Wadepohl, Hubert [VerfasserIn]  |
| Himmel, Hans-Jörg [VerfasserIn]  |
Titel: | Use of crown ether functions as secondary Coordination Spheres for the Manipulation of Ligand-Metal Intramolecular Electron Transfer in Copper-Guanidine Complexes |
Verf.angabe: | Sebastian Haaf, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel |
Jahr: | 2021 |
Umfang: | 12 S. |
Fussnoten: | First published: 24 August 2020 ; Gesehen am 05.11.2021 |
Titel Quelle: | Enthalten in: Chemistry - a European journal |
Ort Quelle: | Weinheim : Wiley-VCH, 1995 |
Jahr Quelle: | 2021 |
Band/Heft Quelle: | 27(2021), 3, Seite 959-970 |
ISSN Quelle: | 1521-3765 |
Abstract: | Intramolecular electron transfer (IET) between a redox-active organic ligand and a metal in a complex is of fundamental interest and used in a variety of applications. In this work it is demonstrated that secondary coordination sphere motifs can be applied to trigger a radical change in the electronic structure of copper complexes with a redox-active guanidine ligand through ligand-metal IET. Hence, crown ether functions attached to the ligand allow the manipulation of the degree of IET between the guanidine ligand and the copper atom through metal encapsulation. |
DOI: | doi:10.1002/chem.202003469 |
URL: | kostenfrei: Volltext: https://doi.org/10.1002/chem.202003469 |
| kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202003469 |
| DOI: https://doi.org/10.1002/chem.202003469 |
Datenträger: | Online-Ressource |
Sprache: | eng |
Sach-SW: | copper |
| guanidine |
| intramolecular electron transfer |
| redox-active ligands |
| secondary coordination sphere |
K10plus-PPN: | 1776279891 |
Verknüpfungen: | → Zeitschrift |
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Lokale URL UB: | Zum Volltext |
Use of crown ether functions as secondary Coordination Spheres for the Manipulation of Ligand-Metal Intramolecular Electron Transfer in Copper-Guanidine Complexes / Haaf, Sebastian [VerfasserIn]; 2021 (Online-Ressource)
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