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Verfasst von:Ueberricke, Lucas [VerfasserIn]   i
 Schwarz, Julia [VerfasserIn]   i
 Ghalami, Farhad [VerfasserIn]   i
 Matthiesen, Maik [VerfasserIn]   i
 Rominger, Frank [VerfasserIn]   i
 Elbert, Sven [VerfasserIn]   i
 Zaumseil, Jana [VerfasserIn]   i
 Elstner, Marcus [VerfasserIn]   i
 Mastalerz, Michael [VerfasserIn]   i
Titel:Triptycene end-capped benzothienobenzothiophene and naphthothienobenzothiophene
Verf.angabe:Lucas Ueberricke, Julia Schwarz, Farhad Ghalami, Maik Matthiesen, Frank Rominger, Sven M. Elbert, Jana Zaumseil, Marcus Elstner, and Michael Mastalerz
Jahr:2020
Umfang:10 S.
Fussnoten:First published: 05 May 2020 ; Gesehen am 12.11.2021
Titel Quelle:Enthalten in: Chemistry - a European journal
Ort Quelle:Weinheim : Wiley-VCH, 1995
Jahr Quelle:2020
Band/Heft Quelle:26(2020), 55, Seite 12596-12605
ISSN Quelle:1521-3765
Abstract:Previously it was demonstrated that triptycene end-capping can be used as a crystal engineering strategy to direct the packing of quinoxalinophenanthrophenazines (QPPs) towards cofacially stacked π dimers with large molecular overlap resulting in high charge transfer integrals. Remarkably, this packing motif was formed under different crystallization conditions and with a variety of derivatives bearing additional functional groups or aromatic substituents. Benzothienobenzothiophene (BTBT) and its derivatives are known as some of the best performing compounds for organic field-effect transistors. Here, the triptycene end-capping concept is introduced to this class of compounds and polymorphic crystal structures are investigated to evaluate the potential of triptycene end-caps as synthons for crystal engineering.
DOI:doi:10.1002/chem.202001125
URL:kostenfrei: Volltext ; Verlag: https://doi.org/10.1002/chem.202001125
 kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202001125
 DOI: https://doi.org/10.1002/chem.202001125
Datenträger:Online-Ressource
Sprache:eng
Sach-SW:benzothienobenzothiophene
 charge transfer
 crystal engineering
 triptycene
K10plus-PPN:1777345235
Verknüpfungen:→ Zeitschrift
 
 
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