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Verfasst von:Foschi, Francesco [VerfasserIn]   i
 Synnatschke, Kevin [VerfasserIn]   i
 Grieger, Sebastian [VerfasserIn]   i
 Zhang, Wen-Shan [VerfasserIn]   i
 Wadepohl, Hubert [VerfasserIn]   i
 Schröder, Rasmus R. [VerfasserIn]   i
 Backes, Claudia [VerfasserIn]   i
 Gade, Lutz H. [VerfasserIn]   i
Titel:Luminogens for aggregation-induced emission via titanium-mediated double nucleophilic addition to 2,5-dialkynylpyridines
Titelzusatz:formation and transformation of the emitting aggregates
Verf.angabe:Francesco Foschi, Kevin Synnatschke, Sebastian Grieger, Wen-Shan Zhang, Hubert Wadepohl, Rasmus R. Schröder, Claudia Backes, and Lutz H. Gade
Jahr:2020
Umfang:12 S.
Fussnoten:Version of record online: February 21, 2020 ; Gesehen am 26.11.2021
Titel Quelle:Enthalten in: Chemistry - a European journal
Ort Quelle:Weinheim : Wiley-VCH, 1995
Jahr Quelle:2020
Band/Heft Quelle:26(2020), 19, Seite 4269-4280
ISSN Quelle:1521-3765
Abstract:New luminogens for aggregation-induced emission (AIE), which are characterized by a branched cross-conjugated 2,6-bis(1,2,2-triarylvinyl)pyridine motif, have been synthesized exploiting the one-pot Ti-mediated tetraarylation of 2,6-bis(arylethynyl)pyridines. Thin layer solid-state emitters were prepared by spin-coating of the luminogens, while AIE-colloidal dispersions were investigated in terms of optical density and scattering behaviour. This has given insight into particle size distributions, time evolution of the aggregation and the influence of different functionalization patterns on the luminescence of molecular aggregates. In particular, a combination of extinction spectroscopy and dynamic light scattering is being proposed as a powerful method for investigating the dynamic aggregation process in AIE-type colloids.
DOI:doi:10.1002/chem.201905611
URL:kostenfrei: Volltext ; Verlag: https://doi.org/10.1002/chem.201905611
 kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201905611
 DOI: https://doi.org/10.1002/chem.201905611
Datenträger:Online-Ressource
Sprache:eng
Sach-SW:aggregation-induced emission
 extinction spectroscopy
 one-pot tetraarylation
 scattering exponent
 titanium tetraisopropoxide
K10plus-PPN:1779614020
Verknüpfungen:→ Zeitschrift
 
 
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