Status: Bibliographieeintrag
Standort: ---
Exemplare:
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| Online-Ressource |
Verfasst von: | Emeljanenko, Dimitri [VerfasserIn]  |
| Kaifer, Elisabeth [VerfasserIn]  |
| Himmel, Hans-Jörg [VerfasserIn]  |
Titel: | Guanidino-functionalised aromatic electron donors at work |
Titelzusatz: | competing hydrogen- and electron-transfer reactions in the course of the synthesis of gold acetylide complexes |
Verf.angabe: | Dimitri Emeljanenko, Elisabeth Kaifer, Hans-Jörg Himmel |
E-Jahr: | 2011 |
Jahr: | 01 June 2011 |
Umfang: | 9 S. |
Fussnoten: | Gesehen am 28.04.2022 |
Titel Quelle: | Enthalten in: European journal of inorganic chemistry |
Ort Quelle: | Weinheim : Wiley-VCH, 1998 |
Jahr Quelle: | 2011 |
Band/Heft Quelle: | (2011), 19, Seite 2975-2983 |
ISSN Quelle: | 1099-0682 |
Abstract: | In this work reactions between [AuCl(PPh3)] and HC≡CAr (Ar = phenyl, pyridinyl, biphenyl or p-acetylphenyl) in the presence of the nitrogen base and organic electron donor1,2,4,5-tetrakis(N,N′-dimethyl-N,N′-ethyleneguanidino)benzene (1) were studied. Two different product types were isolated and characterised: the neutral AuI acetylides[Au(C≡CAr)PPh3] and the salts (1)[Au(C≡CAr)2]2. They can be easily separated from each other by crystallisation under different conditions. The yields strongly depend on the applied acetylene. While the first product type underlines the basic properties of 1, the second product type highlights its electron-donor capacity. The experimental results indicate reduction of the C−H protons to H2 and two-electron oxidation of 1. Thermal decomposition of (1)[Au(C≡CAr)2]2 (Ar = Ph) leads back to the neutral guanidine and Au nanoparticles (accompanied by oxidative coupling of the two acetylide ligands). |
DOI: | doi:10.1002/ejic.201100160 |
URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/ejic.201100160 |
| Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201100160 |
| DOI: https://doi.org/10.1002/ejic.201100160 |
Datenträger: | Online-Ressource |
Sprache: | eng |
Sach-SW: | Acetylides |
| Anions |
| C-H acidity |
| Electron transfer |
| Gold |
| Guanidine |
K10plus-PPN: | 1800498233 |
Verknüpfungen: | → Zeitschrift |
Guanidino-functionalised aromatic electron donors at work / Emeljanenko, Dimitri [VerfasserIn]; 01 June 2011 (Online-Ressource)
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