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| Verfasst von: | Azam, Mohammad [VerfasserIn]  |
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| | Velmurugan, Gunasekaran [VerfasserIn] |
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| | Trzesowska-Kruszynska, Agata [VerfasserIn] |
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| | Al-Resayes, Saud I. [VerfasserIn] |
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| | Kruszynski, Rafal [VerfasserIn] |
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| | Venuvanalingam, Ponnambalam [VerfasserIn] |
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| Titel: | A bowl-shaped phenoxido-bridged binuclear zinc complex |
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| Titelzusatz: | experimental and theoretical studies |
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| Verf.angabe: | Mohammad Azam, Gunasekaran Velmurugan, Agata Trzesowska-Kruszynska, Saud I. Al-Resayes, Rafal Kruszynski, Ponnambalam Venuvanalingam |
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| E-Jahr: | 2022 |
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| Jahr: | 19 January 2022 |
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| Umfang: | 10 S. |
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| Fussnoten: | Gesehen am 13.05.2022 |
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| Titel Quelle: | Enthalten in: Inorganica chimica acta |
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| Ort Quelle: | New York, NY [u.a.] : Elsevier, 1967 |
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| Jahr Quelle: | 2022 |
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| Band/Heft Quelle: | 534(2022), Artikel-ID 120807, Seite 1-10 |
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| ISSN Quelle: | 0020-1693 |
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| Abstract: | A new dinuclear zinc coordination complex with di(μ-alkoxido) bridge obtained from [[H2L = N,N-(salicyaldene)-1,3-diaminopropan-2-ol] was investigated by IR, 1H- & 13C NMR spectroscopy. Single crystal X-ray analysis reveals that the Zn1 atom in the title complex is five coordinated and bound to two alkoxide atoms, two nitrogen atoms, and a chloride ion at apical position in distorted square pyramid geometry, while the second central cation, Zn2, is four coordinated and its O2Cl2 coordination environment is distorted tetrahedral. The single-crystal X-ray crystallographic measurements and DFT calculations reveal that the complex has a bowl-like structure. Hirschfeld surface analysis, energy frameworks QTAIM, NBO, and EDA analyses show clearly that the structure contains a variety of classical and non-classical interactions that help to extend the crystal net dimension. TGA is used to investigate the stability of the structure of the title complex. |
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| DOI: | doi:10.1016/j.ica.2022.120807 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext: https://doi.org/10.1016/j.ica.2022.120807 |
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| | Volltext: https://www.sciencedirect.com/science/article/pii/S0020169322000196 |
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| | DOI: https://doi.org/10.1016/j.ica.2022.120807 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | Crystal structure |
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| | DFT |
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| | Dinuclear zinc complex |
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| | Hirshfeld surface analysis |
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| K10plus-PPN: | 1801725527 |
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| Verknüpfungen: | → Zeitschrift |
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¬A¬ bowl-shaped phenoxido-bridged binuclear zinc complex / Azam, Mohammad [VerfasserIn]; 19 January 2022 (Online-Ressource)
