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| Verfasst von: | Michalsky, Ina [VerfasserIn]  |
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| | Gensch, Viktoria [VerfasserIn] |
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| | Walla, Christian [VerfasserIn] |
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| | Hoffmann, Marvin [VerfasserIn] |
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| | Rominger, Frank [VerfasserIn] |
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| | Oeser, Thomas [VerfasserIn] |
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| | Tegeder, Petra [VerfasserIn] |
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| | Dreuw, Andreas [VerfasserIn] |
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| | Kivala, Milan [VerfasserIn] |
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| Titel: | Fully bridged triphenylamines comprising five- and seven-membered rings |
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| Verf.angabe: | Ina Michalsky, Viktoria Gensch, Christian Walla, Marvin Hoffmann, Frank Rominger, Thomas Oeser, Petra Tegeder, Andreas Dreuw, and Milan Kivala |
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| Jahr: | 2022 |
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| Umfang: | 6 S. |
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| Fussnoten: | First published: 16 March 2022 ; Gesehen am 22.09.2022 |
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| Titel Quelle: | Enthalten in: Chemistry - a European journal |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1995 |
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| Jahr Quelle: | 2022 |
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| Band/Heft Quelle: | 28(2022), 34, Artikel-ID e202200326, Seite 1-6 |
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| ISSN Quelle: | 1521-3765 |
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| Abstract: | A family of fully bridged triphenylamines with embedded 5- and 7-membered rings is presented. The compounds are potent electron donors capable to undergo donor/acceptor interactions with strong cyano-based acceptors both in the solid state and solution. These interactions were evaluated by IR and UV/vis spectroscopy as well as X-ray crystallography. The vinylene-bridged compound was oxidized to the corresponding 1,2-diketone which readily underwent acid-catalyzed condensation with selected 1,2-phenylenediamines. The resulting π-extended quinoxaline derivatives represent valuable building blocks for the development of functional chromophores upon appropriate functionalization. |
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| DOI: | doi:10.1002/chem.202200326 |
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| URL: | kostenfrei: Volltext: https://doi.org/10.1002/chem.202200326 |
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| | kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202200326 |
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| | DOI: https://doi.org/10.1002/chem.202200326 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | bridged triarylamines |
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| | charge transfer |
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| | co-crystallization |
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| | electron donor |
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| | N-heterocycle |
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| K10plus-PPN: | 1817307657 |
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| Verknüpfungen: | → Zeitschrift |
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| Lokale URL UB: |  Zum Volltext |
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Fully bridged triphenylamines comprising five- and seven-membered rings / Michalsky, Ina [VerfasserIn]; 2022 (Online-Ressource)
