Status: Bibliographieeintrag
Standort: ---
Exemplare:
---
| |  Online-Ressource |
|---|
| Verfasst von: | Miguez‐Lago, Sandra [VerfasserIn]  |
|---|
| | Gliemann, Bettina D. [VerfasserIn] |
|---|
| | Kivala, Milan [VerfasserIn] |
|---|
| | Cid, María Magdalena [VerfasserIn] |
|---|
| Titel: | A chiral molecular cage comprising diethynylallenes and N-heterotriangulenes for enantioselective recognition |
|---|
| Verf.angabe: | Sandra Míguez-Lago, Bettina D. Gliemann, Milan Kivala, and María Magdalena Cid |
|---|
| Jahr: | 2021 |
|---|
| Umfang: | 6 S. |
|---|
| Fussnoten: | First published: 09 August 2021 ; In memory of Professor François Diederich ; Gesehen am 23.09.2022 |
|---|
| Titel Quelle: | Enthalten in: Chemistry - a European journal |
|---|
| Ort Quelle: | Weinheim : Wiley-VCH, 1995 |
|---|
| Jahr Quelle: | 2021 |
|---|
| Band/Heft Quelle: | 27(2021), 53, Seite 13352-13357 |
|---|
| ISSN Quelle: | 1521-3765 |
|---|
| Abstract: | Chirality, a characteristic tool of molecular recognition in nature, is often a complement of redox active systems. Scientists, in their eagerness to mimic such sophistication, have designed numerous chiral systems based on molecular entities with cavities, such as macrocycles and cages. In an attempt to combine chirality and redox-active species, in this contribution we report the synthesis and detailed characterization of a chiral shape-persistent molecular cage based on the combination of enantiopure diethynylallenes and electron-rich bridged triarylamines, also known as N-heterotriangulenes. Its ability for chiral recognition in solution was revealed through UV/vis titrations with enantiopure helicenes. |
|---|
| DOI: | doi:10.1002/chem.202101801 |
|---|
| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.1002/chem.202101801 |
|---|
| | Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202101801 |
|---|
| | DOI: https://doi.org/10.1002/chem.202101801 |
|---|
| Datenträger: | Online-Ressource |
|---|
| Sprache: | eng |
|---|
| Sach-SW: | allenes |
|---|
| | bridged triarylamines |
|---|
| | chirality |
|---|
| | molecular cages |
|---|
| | molecular recognition |
|---|
| K10plus-PPN: | 1817332678 |
|---|
| Verknüpfungen: | → Zeitschrift |
|---|
¬A¬ chiral molecular cage comprising diethynylallenes and N-heterotriangulenes for enantioselective recognition / Miguez‐Lago, Sandra [VerfasserIn]; 2021 (Online-Ressource)
68966952
