Fusion of a 1,3-diboraruthenocene to form a slipped μ-hexahydrotetraboranaphthalene triple-decker complex with two axial C-H bonds$3hElena V. Mutseneck, Hubert Wadepohl, Markus Enders, Alexander R. Kudinov, and Walter Siebert

• Verfasst von: Mutseneck, Elena V. [VerfasserIn]
• Verfasst von: Wadepohl, Hubert [VerfasserIn]
• Verfasst von: Enders, Markus [VerfasserIn]
• Verfasst von: Kudinov, Alexander R. [VerfasserIn]
• Verfasst von: Siebert, Walter [VerfasserIn]
• Titel: Fusion of a 1,3-diboraruthenocene to form a slipped μ-hexahydrotetraboranaphthalene triple-decker complex with two axial C-H bonds$3hElena V. Mutseneck, Hubert Wadepohl, Markus Enders, Alexander R. Kudinov, and Walter Siebert
• Jahr: 2009
• Umfang: 3 S.
• Fussnoten: μ mu ; First published: 30 January 2009 ; Gesehen am 30.11.2022
• Titel Quelle: Enthalten in: Angewandte Chemie / International edition
• Ort Quelle: Weinheim : Wiley-VCH, 1962
• Jahr Quelle: 2009
• Band/Heft Quelle: 48(2009), 8, Seite 1429-1431
• ISSN Quelle: 1521-3773
• DOI: doi:10.1002/anie.200802945
• Datenträger: Online-Ressource
• Sprache: eng
• Sach-SW: boron
• Sach-SW: CH bonds
• Sach-SW: density functional calculations
• Sach-SW: ruthenium
• Sach-SW: sandwich complexes
• K10plus-PPN: 1824066430

Abstract

Colliding double deckers: Addition of zinc to a reaction mixture of [Cp*RuCl4]/pentamethyl-2,3-dihydro-1,3-diborole (C3B2Me5H) in THF leads to three known double- and triple-decker complexes of [C3B2Me5]−, and unexpectedly to the slipped triple-decker (see picture) with two fused diborole rings. The endo CH bonds of two MeCH groups donate two additional electrons to achieve the stable 34 VE configuration.