| Online-Ressource |
Verfasst von: | Filbeck, Erik [VerfasserIn]  |
| Kistner, Lucas [VerfasserIn]  |
| Vogler, Daniel [VerfasserIn]  |
| Bučak Gasser, David [VerfasserIn]  |
| Flórido Martins, Lilliana [VerfasserIn]  |
| Schöner, Maximilian [VerfasserIn]  |
| Kaifer, Elisabeth [VerfasserIn]  |
| Himmel, Hans-Jörg [VerfasserIn]  |
Titel: | Synthesis of symmetrically and unsymmetrically substituted cationic diborane(4) compounds with distinct structural motifs and properties |
Verf.angabe: | Erik Filbeck, Lucas Kistner, Daniel Vogler, David Bučak Gasser, Lilliana Flórido Martins, Maximilian Schöner, Elisabeth Kaifer, and Hans-Jörg Himmel |
E-Jahr: | 2022 |
Jahr: | 14 November 2022 |
Umfang: | 12 S. |
Fussnoten: | Gesehen am 19.12.2022 |
Titel Quelle: | Enthalten in: European journal of organic chemistry |
Ort Quelle: | Weinheim : Wiley-VCH Verl., 1998 |
Jahr Quelle: | 2022 |
Band/Heft Quelle: | (2022), 43, Artikel-ID e202201105, Seite 1-12 |
ISSN Quelle: | 1099-0690 |
Abstract: | The introduction of electron-donating, bridging guanidinate substituents in diborane(4) compounds allows the synthesis of a variety of new cationic diborane(4) compounds. In this work, strategies for the directed synthesis of cationic di- and tetraboron compounds are presented, leading to the synthesis and complete characterization of several new compounds with distinct structural motifs, all exhibiting BII atoms directly bound to each other. Hence, we report on tetracationic donor-acceptor cyclophanes with diboron donor linkers and organic π-acceptor units, on paddlewheel-type cationic diboranes, and on unsymmetrically-substituted monocationic diboranes. |
DOI: | doi:10.1002/ejoc.202201105 |
URL: | kostenfrei: Volltext: https://doi.org/10.1002/ejoc.202201105 |
| kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.202201105 |
| DOI: https://doi.org/10.1002/ejoc.202201105 |
Datenträger: | Online-Ressource |
Sprache: | eng |
Sach-SW: | Boron |
| Cation |
| Diborane |
| Nucleophile |
| Substitution |
K10plus-PPN: | 1827858117 |
Verknüpfungen: | → Zeitschrift |
|
|
| |
Lokale URL UB: | Zum Volltext |
Synthesis of symmetrically and unsymmetrically substituted cationic diborane(4) compounds with distinct structural motifs and properties / Filbeck, Erik [VerfasserIn]; 14 November 2022 (Online-Ressource)