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| Verfasst von: | Vethacke, Vanessa [VerfasserIn]  |
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| | Claus, Vanessa [VerfasserIn] |
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| | Dietl, Martin C. [VerfasserIn] |
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| | Ehjeij, Daniel [VerfasserIn] |
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| | Meister, Arne [VerfasserIn] |
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| | Huber, Jonas F. [VerfasserIn] |
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| | Paschai Darian, Leon K. [VerfasserIn] |
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| | Rudolph, Matthias [VerfasserIn] |
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| | Rominger, Frank [VerfasserIn] |
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| | Hashmi, A. Stephen K. [VerfasserIn] |
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| Titel: | Access to unsymmetrically substituted diaryl Gold N-Acyclic Carbene (NAC) and N-Heterocyclic Carbene (NHC) complexes via the isonitrile route |
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| Verf.angabe: | Vanessa Vethacke, Vanessa Claus, Martin C. Dietl, Daniel Ehjeij, Arne Meister, Jonas F. Huber, Leon K. Paschai Darian, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
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| Jahr: | 2022 |
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| Umfang: | 19 S. |
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| Fussnoten: | Version of record online: October 18, 2021 ; Gesehen am 24.03.2023 |
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| Titel Quelle: | Enthalten in: Advanced synthesis & catalysis |
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| Ort Quelle: | Weinheim : Wiley-VCH, 2001 |
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| Jahr Quelle: | 2022 |
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| Band/Heft Quelle: | 364(2022), 3, Seite 536-554 |
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| ISSN Quelle: | 1615-4169 |
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| Abstract: | A variety of unsymmetric diaryl gold N-acyclic carbene (NAC) complexes was synthesized via the isonitrile route by three different methods: (a) solvent free in a melt, (b) mechanochemically and (c) in THF at room temperature. The latter method can also be used to synthesize unsaturated gold NHC complexes. These methods overall offer access to a broad array of new complexes and remove one of the previous limitations of the isonitrile route to NAC and NHC complexes of gold, namely the inability to react with the less nucleophilic aromatic amines. The new complexes also proved to be successful as pre-catalysts in the gold-catalyzed phenol synthesis. |
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| DOI: | doi:10.1002/adsc.202101000 |
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| URL: | kostenfrei: Volltext: https://doi.org/10.1002/adsc.202101000 |
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| | kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.202101000 |
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| | DOI: https://doi.org/10.1002/adsc.202101000 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | aryl amines |
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| | carbene complexes |
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| | gold |
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| | isonitriles |
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| | NAC complexes |
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| | NHC complexes |
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| K10plus-PPN: | 1840029161 |
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| Verknüpfungen: | → Zeitschrift |
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| Lokale URL UB: |  Zum Volltext |
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Access to unsymmetrically substituted diaryl Gold N-Acyclic Carbene (NAC) and N-Heterocyclic Carbene (NHC) complexes via the isonitrile route / Vethacke, Vanessa [VerfasserIn]; 2022 (Online-Ressource)
