Gold and organocatalysis combined

• Verfasst von: Hashmi, A. Stephen K. [VerfasserIn]
• Verfasst von: Hubbert, Christoph [VerfasserIn]
• Titel: Gold and organocatalysis combined
• Verf.angabe: A. Stephen K. Hashmi and Christoph Hubbert
• E-Jahr: 2010
• Jahr: [February 1, 2010]
• Umfang: 3 S.
• Illustrationen: Illustrationen
• Fussnoten: First published: 26 January 2010 ; Gesehen am 24.03.2023
• Titel Quelle: Enthalten in: Angewandte Chemie. International edition
• Ort Quelle: Weinheim : Wiley-VCH, 1998
• Jahr Quelle: 2010
• Band/Heft Quelle: 49(2010), 6, Seite 1010-1012
• ISSN Quelle: 1521-3773
• DOI: doi:10.1002/anie.200906609
• Datenträger: Online-Ressource
• Sprache: eng
• Bibliogr. Hinweis: Erscheint auch als : Druck-Ausgabe: Hashmi, A. Stephen K., 1963 - : Gold and organocatalysis combined. - 2010
• Sach-SW: chiral acids
• Sach-SW: enantioselective catalysis
• Sach-SW: gold
• Sach-SW: sequential reactions
• K10plus-PPN: 1840088346

Abstract

All that glitters: Binary catalytic systems of gold(I) complexes and chiral Brønsted acids, which were recently reported by the research groups of Dixon and Gong, represent a significant leap forwards in the area of sequential one-pot reactions. The special feature of these reactions is the isolobal analogy of the proton and [LAuI] cations, which requires a delicate balance between the reactivities of the acids and the gold complexes.