| Online-Ressource |
Verfasst von: | Wagner, Philippe [VerfasserIn]  |
| Rominger, Frank [VerfasserIn]  |
| Zhang, Wen-Shan [VerfasserIn]  |
| Gross, Jürgen H. [VerfasserIn]  |
| Elbert, Sven [VerfasserIn]  |
| Schröder, Rasmus R. [VerfasserIn]  |
| Mastalerz, Michael [VerfasserIn]  |
Titel: | Chiral self-sorting of giant cubic [8+12] Salicylimine cage compounds |
Verf.angabe: | Philippe Wagner, Frank Rominger, Wen-Shan Zhang, Jürgen H. Gross, Sven M. Elbert, Rasmus R. Schröder, and Michael Mastalerz |
Jahr: | 2021 |
Umfang: | 9 S. |
Fussnoten: | Gesehen am 21.04.2023 |
Titel Quelle: | Enthalten in: Angewandte Chemie. International edition |
Ort Quelle: | Weinheim : Wiley-VCH, 1998 |
Jahr Quelle: | 2021 |
Band/Heft Quelle: | 60(2021), 16, Seite 8896-8904 |
ISSN Quelle: | 1521-3773 |
Abstract: | Chiral self-sorting is intricately connected to the complicated chiral processes observed in nature and no artificial systems of comparably complexity have been generated by chemists. However, only a few examples of purely organic molecules have been reported so far, where the self-sorting process could be controlled. Herein, we describe the chiral self-sorting of large cubic [8+12] salicylimine cage compounds based on a chiral TBTQ precursor. Out of 23 possible cage isomers only the enantiopure and a meso cage were observed to be formed, which have been unambiguously characterized by single crystal X-ray diffraction. Furthermore, by careful choice of solvent the formation of meso cage could be controlled. With internal diameters of din=3.3-3.5 nm these cages are among the largest organic cage compounds characterized and show very high specific surface areas up to approx. 1500 m2 g−1 after desolvation. |
DOI: | doi:10.1002/anie.202016592 |
URL: | kostenfrei: Volltext: https://doi.org/10.1002/anie.202016592 |
| kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202016592 |
| DOI: https://doi.org/10.1002/anie.202016592 |
Datenträger: | Online-Ressource |
Sprache: | eng |
Sach-SW: | cage compounds |
| chiral |
| imine |
| self-sorting |
| tribenzotriquinacene |
K10plus-PPN: | 1843356708 |
Verknüpfungen: | → Zeitschrift |
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Lokale URL UB: | Zum Volltext |
Chiral self-sorting of giant cubic [8+12] Salicylimine cage compounds / Wagner, Philippe [VerfasserIn]; 2021 (Online-Ressource)