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| Verfasst von: | Wagner, Philippe [VerfasserIn]  |
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| | Rominger, Frank [VerfasserIn] |
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| | Zhang, Wen-Shan [VerfasserIn] |
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| | Gross, Jürgen H. [VerfasserIn] |
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| | Elbert, Sven [VerfasserIn] |
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| | Schröder, Rasmus R. [VerfasserIn] |
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| | Mastalerz, Michael [VerfasserIn] |
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| Titel: | Chiral self-sorting of giant cubic [8+12] Salicylimine cage compounds |
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| Verf.angabe: | Philippe Wagner, Frank Rominger, Wen-Shan Zhang, Jürgen H. Gross, Sven M. Elbert, Rasmus R. Schröder, and Michael Mastalerz |
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| Jahr: | 2021 |
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| Umfang: | 9 S. |
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| Fussnoten: | Gesehen am 21.04.2023 |
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| Titel Quelle: | Enthalten in: Angewandte Chemie |
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| Ort Quelle: | Weinheim : Wiley-VCH, 1887 |
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| Jahr Quelle: | 2021 |
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| Band/Heft Quelle: | 133(2021), 16, Seite 8978-8986 |
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| ISSN Quelle: | 1521-3757 |
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| Abstract: | Chiral self-sorting is intricately connected to the complicated chiral processes observed in nature and no artificial systems of comparably complexity have been generated by chemists. However, only a few examples of purely organic molecules have been reported so far, where the self-sorting process could be controlled. Herein, we describe the chiral self-sorting of large cubic [8+12] salicylimine cage compounds based on a chiral TBTQ precursor. Out of 23 possible cage isomers only the enantiopure and a meso cage were observed to be formed, which have been unambiguously characterized by single crystal X-ray diffraction. Furthermore, by careful choice of solvent the formation of meso cage could be controlled. With internal diameters of din=3.3-3.5 nm these cages are among the largest organic cage compounds characterized and show very high specific surface areas up to approx. 1500 m2 g−1 after desolvation. |
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| DOI: | doi:10.1002/ange.202016592 |
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| URL: | kostenfrei: Volltext: https://doi.org/10.1002/ange.202016592 |
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| | kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202016592 |
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| | DOI: https://doi.org/10.1002/ange.202016592 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | cage compounds |
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| | chiral |
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| | imine |
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| | self-sorting |
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| | tribenzotriquinacene |
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| K10plus-PPN: | 1843357283 |
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| Verknüpfungen: | → Zeitschrift |
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| Lokale URL UB: |  Zum Volltext |
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Chiral self-sorting of giant cubic [8+12] Salicylimine cage compounds / Wagner, Philippe [VerfasserIn]; 2021 (Online-Ressource)
