Reactions of rhodium carbonyl clusters with heterobidentate ligands

• Verfasst von: Gracheva, E. V. [VerfasserIn]
• Verfasst von: Linti, Gerald W. [VerfasserIn]
• Titel: Reactions of rhodium carbonyl clusters with heterobidentate ligands
• Titelzusatz: synthesis and structural characterization of the Rh6(CO)15[(C6H5)2PC6H4N(CH3)2] and {Rh6(CO)15[(C6H5)2PC6H4NH(CH3)2]}[GaX4] cluster compounds
• Verf.angabe: E.V. Gracheva and G. Linti
• Jahr: 2010
• Fussnoten: Received April 8, 2009 ; Gesehen am 28.04.2023
• Titel Quelle: Enthalten in: Russian journal of general chemistry
• Ort Quelle: Dordrecht : Springer Science + Business Media B.V., 1996
• Jahr Quelle: 2010
• Band/Heft Quelle: 80(2010), 3, Seite 414-422
• ISSN Quelle: 1608-3350
• DOI: doi:10.1134/S1070363210030072
• Datenträger: Online-Ressource
• Sprache: eng
• Sach-SW: GaCl
• Sach-SW: General Chemistry
• Sach-SW: Metal Skeleton
• Sach-SW: ORTEP View
• Sach-SW: Rhodium Atom
• K10plus-PPN: 1843832313

Abstract

The reaction of heterobidentate 4-(dimethylamino)phenyldiphenylphosphine with labile cluster Rh6(CO)15(NCMe) yielding a new monosubstituted cluster Rh6(CO)15(Ph2PC6H4NMe2) was described. The reactions of the resulting cluster with GaX3 compounds were studied. The structure of all obtained compounds was completely characterized both in a solid phase and in a solution by X-ray diffraction analysis, mass spectrometry, and IR and polynuclear NMR spectroscopy.