Single crystals of insoluble porous salicylimine cages [data]

• Verfasst von: Holsten, Mattes [VerfasserIn]
• Verfasst von: Elbert, Sven [VerfasserIn]
• Verfasst von: Rominger, Frank [VerfasserIn]
• Verfasst von: Zhang, Wen-Shan [VerfasserIn]
• Verfasst von: Schröder, Rasmus R. [VerfasserIn]
• Verfasst von: Mastalerz, Michael [VerfasserIn]
• Titel: Single crystals of insoluble porous salicylimine cages [data]
• Verf.angabe: Mattes Holsten, Sven Michael Elbert, Frank Rominger, Wen-Shan Zhang, Rasmus R. Schröder, Michael Mastalerz
• Verlagsort: Heidelberg
• Verlag: Universität
• E-Jahr: 2023
• Jahr: 2023-08-23
• Umfang: 1 Online-Ressource (6 Files)
• Fussnoten: Gesehen am 24.08.2023
• DOI: doi:10.11588/data/45FZRY
• Datenträger: Online-Ressource
• Dokumenttyp: Forschungsdaten
• Dokumenttyp: Datenbank
• Sprache: eng
• Bibliogr. Hinweis: Forschungsdaten zu: Holsten, Mattes: Single crystals of insoluble porous salicylimine cages
• Sach-SW: Chemistry
• K10plus-PPN: 1857891317
• K10plus-PPN:
  Universitätsbibliothek
• Lokale URL UB: Zum Volltext

Abstract

Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single-crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas-sorption properties in both morphological states.