Facile two-step synthesis of para-dithienopyrazines [data]

• Verfasst von: Hashmi, A. Stephen K. [VerfasserIn]
• Verfasst von: Hüßler, Christopher [VerfasserIn]
• Verfasst von: Kahle, Justin [VerfasserIn]
• Verfasst von: Dietl, Martin C. [VerfasserIn]
• Verfasst von: Krämer, Petra [VerfasserIn]
• Verfasst von: Rominger, Frank [VerfasserIn]
• Verfasst von: Rudolph, Matthias [VerfasserIn]
• Titel: Facile two-step synthesis of para-dithienopyrazines [data]
• Verf.angabe: A. Stephen K. Hashmi, Christopher Hüßler, Justin Kahle, Martin C. Dietl, Petra Krämer, Frank Rominger, Matthias Rudolph
• Verlagsort: Heidelberg
• Verlag: Universität
• E-Jahr: 2024
• Jahr: 2024-01-31
• Umfang: 1 Online-Ressource (1 File)
• Fussnoten: Finanziert durch: Deutsche Forschungsgemeinschaft, SFB 1249: N-heteropolycycles as functional materials ; Gesehen am 31.01.2024
• DOI: doi:10.11588/data/14RXKL
• Datenträger: Online-Ressource
• Dokumenttyp: Forschungsdaten
• Dokumenttyp: Datenbank
• Sprache: eng
• Bibliogr. Hinweis: Forschungsdaten zu: Hüßler, Christopher, 1995 - : Facile two-step synthesis of para-dithienopyrazines
• Sach-SW: Chemistry
• K10plus-PPN: 1879625504
• K10plus-PPN:
  Universitätsbibliothek
• Lokale URL UB: Zum Volltext

Abstract

N-Heteropolycyclic compounds are valuable building blocks in organic electronic devices. In this work, a convenient route for the synthesis of para-dithienopyrazines from readily available starting materials is described. A cascade of nucleophilic aromatic substitution and subsequent bidirectional hydrothiolation of alkynes was used as a key step. In total, seven new target compounds were synthesized and investigated regarding their photophysical properties. In solution, these molecules act as blue emitters, which turn to green upon addition of an acid, which demonstrates their potential use as proton sensors. Data includes: CV, IR, MS, NMR, UV VIS and XRAY Data for the compounds in the manuscript