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| Verfasst von: | Harrer, Siegfried [VerfasserIn]  |
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| | Schühle, Johannes D. R. [VerfasserIn] |
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| | Neiß, Christian [VerfasserIn] |
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| | Günthert, Marina [VerfasserIn] |
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| | Mittmann, Lena [VerfasserIn] |
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| | Reule, Andrea [VerfasserIn] |
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| | Leitner, Jonas [VerfasserIn] |
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| | Rominger, Frank [VerfasserIn] |
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| | Görling, Andreas [VerfasserIn] |
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| | Kivala, Milan [VerfasserIn] |
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| Titel: | Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes |
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| Verf.angabe: | Siegfried Harrer, Johannes D.R. Schühle, Christian Neiß, Marina Günthert, Lena Mittmann, Andrea Reule, Jonas Leitner, Frank Rominger, Andreas Görling, and Milan Kivala |
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| E-Jahr: | 2024 |
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| Jahr: | July 8, 2024 |
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| Umfang: | 6 S. |
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| Illustrationen: | Illustrationen |
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| Fussnoten: | Gesehen am 11.10.2024 |
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| Titel Quelle: | Enthalten in: European journal of organic chemistry |
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| Ort Quelle: | Weinheim : Wiley-VCH Verl., 1998 |
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| Jahr Quelle: | 2024 |
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| Band/Heft Quelle: | 27(2024), 26, Artikel-ID e202400368, Seite 1-6 |
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| ISSN Quelle: | 1099-0690 |
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| Abstract: | The structural and electronic properties of the dimethylmethylene-bridged P-heterotriangulene have been systematically modulated by functionalization of its phosphorus center. The optoelectronic properties of the obtained derivatives in solution were characterized by UV/Vis absorption and emission spectroscopy, cyclic voltammetry and 31P NMR spectroscopy. The solid state structures were analyzed by X-ray crystallography. The experimental results were corroborated by density functional theory calculations which revealed the crucial influence of the axial substitution on the bowl-shaped geometry of the phosphorus-centered polycyclic scaffold, which is proportional to the s-character of the P−X bond. The advantage of the bowl-shaped P-heterotriangulene scaffold was demonstrated by successful co-crystallization with fullerene C60. |
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| DOI: | doi:10.1002/ejoc.202400368 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
kostenfrei: Volltext: https://doi.org/10.1002/ejoc.202400368 |
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| | kostenfrei: Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.202400368 |
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| | DOI: https://doi.org/10.1002/ejoc.202400368 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | bowl-shaped |
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| | bridged triarylphosphines |
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| | density functional theory calculations |
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| | phosphorus heterocycles |
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| | X-ray crystallography |
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| K10plus-PPN: | 1905507933 |
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| Verknüpfungen: | → Zeitschrift |
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Structural and electronic impacts of the axialsSubstitution at the phosphorus center of C(sp3)-bridged P-heterotriangulenes / Harrer, Siegfried [VerfasserIn]; July 8, 2024 (Online-Ressource)
