A negatively curved nanographene with four embedded heptagons

• Verfasst von: Elbert, Sven [VerfasserIn]
• Verfasst von: Paine, Owen T. A. [VerfasserIn]
• Verfasst von: Kirschbaum, Tobias [VerfasserIn]
• Verfasst von: Schuldt, Moritz P. [VerfasserIn]
• Verfasst von: Weber, Laura [VerfasserIn]
• Verfasst von: Rominger, Frank [VerfasserIn]
• Verfasst von: Mastalerz, Michael [VerfasserIn]
• Titel: A negatively curved nanographene with four embedded heptagons
• Verf.angabe: Sven M. Elbert, Owen T.A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, and Michael Mastalerz
• E-Jahr: 2024
• Jahr: September 27, 2024
• Umfang: 11 S.
• Illustrationen: Illustrationen
• Fussnoten: Gesehen am 26.02.2025
• Titel Quelle: Enthalten in: American Chemical SocietyJournal of the American Chemical Society
• Ort Quelle: Washington, DC : ACS Publications, 1879
• Jahr Quelle: 2024
• Band/Heft Quelle: 146(2024), 40, Seite 27324-27334
• ISSN Quelle: 1520-5126
• DOI: doi:10.1021/jacs.4c09185
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1918587604

Abstract

Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C60 and C70 were studied.