A two-channel thermal dissociation cavity ring-down spectrometer for the detection of ambient NO2, RO2NO2 and RONO2

• Verfasst von: Thieser, Jim [VerfasserIn]
• Verfasst von: Schuster, G. [VerfasserIn]
• Verfasst von: Schuladen, J. [VerfasserIn]
• Verfasst von: Phillips, G. J. [VerfasserIn]
• Verfasst von: Reiffs, A. [VerfasserIn]
• Verfasst von: Parchatka, U. [VerfasserIn]
• Verfasst von: Pöhler, Denis [VerfasserIn]
• Verfasst von: Lelieveld, J. [VerfasserIn]
• Verfasst von: Crowley, J. N. [VerfasserIn]
• Titel: A two-channel thermal dissociation cavity ring-down spectrometer for the detection of ambient NO2, RO2NO2 and RONO2
• Verf.angabe: J. Thieser, G. Schuster, J. Schuladen, G. J. Phillips, A. Reiffs, U. Parchatka, D. Pöhler, J. Lelieveld, J. N. Crowley
• E-Jahr: 2016
• Jahr: 17 February 2016
• Umfang: 24 S.
• Illustrationen: Illustrationen
• Fussnoten: Die 2 im Titel ist jeweils tiefgestellt ; Gesehen am 27.05.2020
• Titel Quelle: Enthalten in: Atmospheric measurement techniques
• Ort Quelle: Katlenburg-Lindau : Copernicus, 2008
• Jahr Quelle: 2016
• Band/Heft Quelle: 9(2016), 2, Seite 553-576
• ISSN Quelle: 1867-8548
• DOI: doi:10.5194/amt-9-553-2016
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1698868324

Abstract

<p><strong>Abstract.</strong> We describe a thermal dissociation cavity ring-down spectrometer (TD-CRDS) for measurement of ambient NO₂, total peroxy nitrates (ΣPNs) and total alkyl nitrates (ΣANs). The spectrometer has two separate cavities operating at ∼ 405.2 and 408.5 nm. One cavity (reference) samples NO₂ continuously from an inlet at ambient temperature, the other samples sequentially from an inlet at 473 K in which PNs are converted to NO₂ or from an inlet at 723 K in which both PNs and ANs are converted to NO₂, difference signals being used to derive mixing ratios of ΣPNs and ΣANs. We describe an extensive set of laboratory experiments and numerical simulations to characterise the fate of organic radicals in the hot inlets and cavity and derive correction factors to account for the bias resulting from the interaction of peroxy radicals with ambient NO and NO₂. Finally, we present the first measurements and comparison with other instruments during a field campaign, outline the limitations of the present instrument and provide an outlook for future improvements.</p>