Status: Bibliographieeintrag
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| Verfasst von: | Ribeiro, Ana Paula da Costa [VerfasserIn]  |
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| | Matias, Inês A. S. [VerfasserIn] |
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| | Zargaran, Poorya [VerfasserIn] |
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| | Hashmi, A. Stephen K. [VerfasserIn] |
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| | Martins, Luísa M. D. R. S. [VerfasserIn] |
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| Titel: | Unprecedented use of NHC gold (I) complexes as catalysts for the selective oxidation of ethane to acetic acid |
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| Verf.angabe: | Ana P.C. Ribeiro, Inês A.S. Matias, Poorya Zargaran, A. Stephen K. Hashmi and Luísa M.D.R.S. Martins |
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| E-Jahr: | 2021 |
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| Jahr: | 31 July 2021 |
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| Umfang: | 9 S. |
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| Teil: | volume:14 |
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| | year:2021 |
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| | number:15 |
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| | elocationid:4294 |
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| | pages:1-9 |
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| | extent:9 |
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| Fussnoten: | Gesehen am 13.09.2021 |
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| Titel Quelle: | Enthalten in: Materials |
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| Ort Quelle: | Basel : MDPI, 2008 |
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| Jahr Quelle: | 2021 |
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| Band/Heft Quelle: | 14(2021), 15, Artikel-ID 4294, Seite 1-9 |
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| ISSN Quelle: | 1996-1944 |
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| Abstract: | The highly efficient eco-friendly synthesis of acetic acid (40% yield) directly from ethane is achieved by the unprecedented use of N-heterocyclic carbene (NHC) and N-heterocyclic oxo-carbene (NHOC) gold(I) catalysts in mild conditions. This is a selective and promising protocol to generate directly acetic acid from ethane, in comparison with the two most used methods: (i) the three-step, capital- and energy-intensive process based on the high-temperature conversion of methane to acetic acid; (ii) the current industrial methanol carbonylation processes, based in iridium and expensive rhodium catalysts. Green metrics determinations highlight the environmental advantages of the new ethane oxidation procedure. Comparison with previous reported published catalysts is performed to highlight the features of this remarkable protocol. |
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| DOI: | doi:10.3390/ma14154294 |
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| URL: | Bitte beachten Sie: Dies ist ein Bibliographieeintrag. Ein Volltextzugriff für Mitglieder der Universität besteht hier nur, falls für die entsprechende Zeitschrift/den entsprechenden Sammelband ein Abonnement besteht oder es sich um einen OpenAccess-Titel handelt.
Volltext ; Verlag: https://doi.org/10.3390/ma14154294 |
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| | Volltext: https://www.mdpi.com/1996-1944/14/15/4294 |
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| | DOI: https://doi.org/10.3390/ma14154294 |
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| Datenträger: | Online-Ressource |
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| Sprache: | eng |
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| Sach-SW: | acetic acid |
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| | ethane oxidation |
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| | green metrics |
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| | NHC gold (I) complex |
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| | NHOC gold (I) complex |
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| K10plus-PPN: | 177006155X |
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| Verknüpfungen: | → Zeitschrift |
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Unprecedented use of NHC gold (I) complexes as catalysts for the selective oxidation of ethane to acetic acid / Ribeiro, Ana Paula da Costa [VerfasserIn]; 31 July 2021 (Online-Ressource)
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