Morphology and agglomeration control of LiMnPO4 micro- and nanocrystals

• Verfasst von: Neef, Christoph [VerfasserIn]
• Verfasst von: Jähne, Carsten [VerfasserIn]
• Verfasst von: Meyer, Hans-Peter [VerfasserIn]
• Verfasst von: Klingeler, Rüdiger [VerfasserIn]
• Titel: Morphology and agglomeration control of LiMnPO4 micro- and nanocrystals
• Verf.angabe: Christoph Neef, Carsten Jähne, Hans-Peter Meyer, and Rüdiger Klingeler
• E-Jahr: 2013
• Jahr: May 21, 2013
• Umfang: 7 S.
• Fussnoten: Im Titel ist die Zahl "4" tiefgestellt ; Gesehen am 08.12.2021
• Titel Quelle: Enthalten in: Langmuir
• Ort Quelle: Washington, DC : ACS Publ., 1985
• Jahr Quelle: 2013
• Band/Heft Quelle: 29(2013), 25, Seite 8054-8060
• ISSN Quelle: 1520-5827
• DOI: doi:10.1021/la3046498
• Datenträger: Online-Ressource
• Sprache: eng
• K10plus-PPN: 1780190611

Abstract

Microwave-assisted hydrothermal synthesis was used to grow LiMnPO4 micro- and nanocrystals from acetate precursors. By appropriate adjustment of the precursor concentration and the pH-value of the reactant, the product composition and purity along with the crystal size can be manipulated, resulting in particle-dimensions from around 10 μm down to a few 100 nm. Prisms and plates with hexagonal basal faces as well as cuboid and rod-like particles were produced. The effects on the crystal morphology as well as on the materials texture and agglomeration tendency are discussed and a comprehensive agglomeration phase diagram is constructed.